solid state photochromism of spiropyrans固态spiropyrans对光反应变色.pdfVIP

Vol. 07 INTERNATIONAL JOURNAL OF PHOTOENERGY 2005 Solid state photochromism of spiropyrans B. S. Lukyanov,1 A. V. Metelitsa,1 N. A. Voloshin,1 Yu. S. Alexeenko,1 M. B. Lukyanova,1 G. T. Vasilyuk,2 S. A. Maskevich,2 and E. L. Mukhanov1 1 Institute of Physical and Organic Chemistry, Rostov State University, Rostov-on-Don, 344090, Russia 2 Y. Kupala State University of Grodno, Ozheshko 22, Grodno 230023, Belarus Abstract. A series of spiropyrans possessing photochromic properties in solid state were investigated. UV irradiation (λmax = 365 nm) of the thin vacuum deposited spiropyran films results in conversion of the colorless form to the photocolored one. The reaction is photochemically and thermally reversible. The photochromic activity of the solid material and polystyrene matrix has been compared. Raman spectroscopy has been used for studying the influence of metallic surface on the adsorbed spiropyran layers. 1. INTRODUCTION Electronic absorption spectra of the spiropyran solid films before and after irradiation have been de- An active research work is carried out all over the world tected by using “Specord UV VIS” spectrophotometer in the field of nonsilvered light sensitive materials, such equipped with special rotating mirror. The vacuum as organic photochromic compounds capable of col- thermal deposition process was carried out for