surface photochemistry photodegradation study of pyrene adsorbed onto microcrystalline cellulose and silica表面光化学光降解研究芘的吸附到微晶纤维素,二氧化硅.pdfVIP

Vol. 06 INTERNATIONAL JOURNAL OF PHOTOENERGY 2004 Surface photochemistry: Photodegradation study of pyrene adsorbed onto microcrystalline cellulose and silica A. S. Oliveira,1,† L. F. Vieira Ferreira,1 J. P. Da Silva,1,2 and J. C. Moreira3 1 Centro de Química-Física Molecular - Complexo Interdisciplinar, Instituto Superior Técnico, 1096 Lisboa Codex, Portugal 2 FCT, Universidade do Algarve, Campus de Gambelas, 8005-139 Faro, Portugal 3 Centro de Estudos da Saúde do Trabalhador e Ecologia Humana, ENSP, Fundação Oswaldo Cruz, Rua Leopoldo Bulhões 1480, Rio de Janeiro, RJ, 21041-210, Brazil Abstract. Ground-state diffuse reflectance, time resolved laser-induced luminescence, diffuse reflectance laser flash-photolysis transient absorption and chromatographic techniques were used to elucidate the pho- todegradation processes of pyrene adsorbed onto microcrystalline cellulose and silica. Ground-state diffuse reflectance showed that on both substrates low concentrations display absorption of pyrene monomers. At high concentrations spectral changes attributed to aggregate formation were observed. Laser induced fluo- rescence showed that pyrene onto microcrystalline cellulose mainly presents fluorescence from monomers, while for silica, excimer-like emission was observed from low surface loadings ( ≥ 0.5 µmol g−1). Transient absorption and photodegradation studies were performed at concentrations where mainly monomers exist. On silica, pyrene presents transient absorption from its radical cation. On microcrystalline cellulose both radical cation, radical anion and