二液型浅色聚亚醯胺树脂之研究.DOC

中文摘要 本研究是利用2,2-Bis(4-hydroxylphenylhexafluoropropane與2-Chloro-5-nitrobenzotrifluoride進行親核取代反應，先合成二硝基化合物，再將其硝基還原成胺基而得二胺單體2,2-Bis[4-(4-amino-2- trifluoromethylphenoxy)phenyl]hexafluoropropane，並且使用DSC測量其熔點、FTIR與NMR鑑定其結構。 將所合成的二胺及數種市售品二胺與二酐合成一系列主鏈結構不同的聚亞醯胺薄膜，不同結構包含醚基、碸基、三氟甲基、六氟異丙烯基等。利用FTIR鑑定其結構、GPC測量其分子量、UV-vis鑑定其光學特性如CIELAB座標、截止波長(cutoff wavelength)、黃色度(yellowness index)，TGA測量其熱穩定性。發現活化基於酐側或去活化基於胺側可以降低聚亞醯胺顏色，而含氟單體也可以有效降低聚亞醯胺顏色。在二胺固定的情況之下，酐側的基團影響聚亞醯胺膜的顏色由深至淺的順序是：－SO2－ － －C(CF3)2－ －O－；在二酐固定的情況之下，胺側的基團影響聚亞醯胺膜的顏色由深至淺的順序是：－O－ －CH2－ －SO2－ siloxane。 比較其顏色後，選擇合適的單體配製二液型淺色聚亞醯胺樹脂，並且使用FTIR鑑定其結構、GPC測定其分子量。使用環氧樹脂與配製出來的聚亞醯胺溶液交聯，可得高透光性之聚亞醯胺交聯膜。並且使用FTIR鑑定其結構、UV-vis鑑定其光學特性、TGA測定其熱穩定性。發現其膜透明性佳，且有足夠的耐熱性。 英文摘要 A new diamine monomer, 2,2-bis[4-(4-amino-2-trifluoromethyl phenoxy)phenyl]hexafluoropropane, was successfully synthesized from 2,2-bis(4- hydroxylphenyl)hexafluoropropane and 2-chloro-5- nitrobenzotrifluoride via two-step method which underwent nucleophilic substitution and oxdation- reduction reaction. The synthesized diamine was identified by DSC, FTIR and 1H NMR. PI films with different functional groups, such as ether, sulfone, trifluoromethyl, hexafluoropropyl, on the backbone were synthesized from several purchased dianhydrides and diamines (including a newly synthesized one) via a typical two-step method. Completely imidized PIs were identified by FTIR. The properties such as molecular weight, thermal ability and optical properties as CIE color space, cutoff wavelength, and yellowness indices of the PI films were determined by GPC, TGA and UV-vis, respectively. Light color of PI films was observed when the activing group in anhydride side of PI or the deactiving group in amine side of PI. Fluoride-containing monomer also may lighten the color of PI films. In the system for the same diamine, influence order of varied group in anhydride side on color of the PI films was as follows: －SO2－ － －C(CF3)2－ －O－ (from deep to light); In the system for the same dianhydride, in