二甲基二烯丙基氯化铵与丙烯酸或丙烯酸羟乙酯共聚-河北工业科技.PDF

27 5 河 北 工 业 科 技 Vol. 27, No . 5 2010 9 H ebei Journal of Industrial Science and T echnolog Sept. 20 10 : 1008- 1534( 2010) 05-0288- 06 , , , , ( 河北科技大学理学院, 河北石家庄 050018) : 以过硫酸钾-亚硫酸氢钠为引发剂, 研究了二甲基二 丙基氯化铵( DM DAAC) 分别与丙 酸( AA) 及丙 酸羟乙酯( HEA) 的水溶液自由基共聚合反应采用膨胀计法测定共聚反应速率, 考察了引发剂浓度单体浓度反应温度对共聚反应速率的影响结果表明, 随着引发剂浓度单体 浓度和反应温度的提高, 共聚反应速率增大建立DMDAAC 与AA 共聚反应的动力学关系式为 0. 690 2 1. 336 - 8 244/ T R P [ I] [ M ] e , 测得该共聚反应表观活化能为68. 54 kJ/ mol; DM DAAC 和HEA 共 1. 089 0 0. 833 - 12 255/ T 聚反应的动力学关系式为 R P [ I] [ M ] e , 该共聚反应的表观活化能 Ea 为 101. 89 kJ/ mol : 二甲基二 丙基氯化铵; 丙 酸; 丙 酸羟乙酯; 共聚; 聚合动力学 : O631. 5 : A Stud on copol merization kinetics of dimeth ldiall lammonium chloride and acr lic acid or 2-h drox eth l acr late CAO Li-na, T IAN Zh-i ing , LU O Qing-zhi, WANG De-song, WEI Xiao-jing ( College of Sciences, Hebei Universit of Science and T echnolog , Shijiazhuang Hebei 0500 18, China) Abstract: The free radical copol merization of dimeth ldiall lammonium chloride ( DMDAA C) with acr lic acid( AA) or 2- h drox eth l acr late ( H EA) w ere carried out in aqueous solution using potassium persulfate and sodium bisulfite as the initia- tor. The effects of initiator concent rations, monomer concentrations and reaction temperatures on copol merization rates, de- termined b the dilatomet er met hod, w ere investigated. It is found t hat copol merization rates increase w ith the increase of ini- t iator concentrations, monomer concent rations and reaction temperatures. The copol merization d namic relationships were ob- 0. 690 2 1. 336 - 8 244/ T 1. 089 0 0.833 - 12 25