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SEMICONDUCTOR Harnessing Diamond(半导体利用钻石)
SEMICONDUCTOR
Harnessing
Diamond
Exploring effi cient
electrochemical advanced
Electrodes oxidation process of
industrial wastewater
By Hossein Zarrin, Tim Mollart Bryan Kumfer
dvanced oxidation processes (AOPs) can mineralize re- required to harness its notable properties. BDD is produced
calcitrant organic and inorganic contaminants in toxic using a form of chemical vapor deposition (CVD), where wafers
Aand biocidal wastewater streams that are diicult to of polycrystalline diamond are grown outside the normal
treat by other means via the creation of hydroxyl radicals. Most high temperature and pressure region of the phase diagram
practical AOPs use a strong oxidizing reagent such as hydrogen for diamond. h e extreme overpotential at both the anode
peroxide or hypochlorite. Electrochemical-based AOPs are and cathode surfaces required the development of a grade of
attractive as they do not require purchase, storage and han- bulk freestanding (i.e., not attached to a substrate) BDD, that
dling of reactive reagents, and are ef ective even on relatively is robust enough to survive these extreme electrochemical
small-scale eluent streams. However, electrochemical-based conditions. Capable of operating at more than 20,000 amperes
AOPs have been largely unavailable and thus far inef ective per sq meter, Element Six’s Electrochemical Processing grade
as a commercially feasible electrode that can withstand the BDD has a proven working lifetime of greater than eight years
har
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