聚N-乙烯基甲酰胺碱性水解反应动力学的分析研究.pdfVIP

聚乙燎币酸敞碱性承瓣蕊癌妨力攀疆究 浅容提要 为了将聚乙烯甲酰胺(PNVF)碱性水解反应应用于生产实践， 本研究在深讨PNVF碱性水繇反应拳慧簿、确定羲基生成量彝碱鹚渣 耗赞物质的蚤的比为2：l的恭础上，对其反应动力学进行研究。得 是影嘞反应逸搴常数麓一个妻要因素；《3)反应速搴常数随NaOH 浓度增大呈折线式上井，即反应速率常数在一定碱浓度范围内近似 相等，超过这一范辫j速率常数有较大蕊度妁上井；≤4)提嶷碱蟋 浓度可降低反应的渗托能。 关穗蠲：聚乙烯警袁磊；酸遣囊求舞；动羁 聚乙瞒零酸鹱城瞧衣瓣彝斑秘力学鹾宠 Abstract To basic apply hydrolysisofpolyvinylfomlamide(PNVF)to productivepractice， was thekineticsofthereaction of whichthestoichiometricratio studied，before PNVFand 2：lhadbeen andthat sodium determined hydroxidebeing the,regularity ofthe hadbeen some reaction discussedj?为erewere conclusionscanbedrawed fromtheresults：a)therate wasoffirstorderwith to幻也PNVF equation respect concentrationandsodium absolute ofthe instead concentration；坟the hydroxide of isonethe to relativeconcentrationNaOH of factorswhich important contribute the rate theconcentrationofNaoH rateconstant constant；c)as grows，the steady in a is rate at arisesafbrmlikefotd the constantis the line，that appmximatelyequal certain ofNaOHconcentrationbutascends outofthe