分步还原法制备电子浆料用球形银粉及其形貌与粒径 morphology and particle size of micro spherical silver fabricated by multistep reduction.pdfVIP

第2 1 卷第1 期 粉末冶金材料科学与工程 2016 年2 月 Vol.2 1 No. 1 Materials Science and Engineering of Powder Metallurgy Feb. 2016 分步还原法制备电子浆料用球形 银粉及其形貌与粒径 李碧渊，甘卫平，黎应芬，周健，王晓庆 ( 中南大学 材料科学与工程学院，长沙 410083) 摘要：采用分步还原法制备银粉，即以硝酸银为银源，硼氢化钠为还原剂制备出晶种，然后还原硝酸银制备银粉， 通过扫描电镜(SEM)和X射线衍射分析，研究还原剂的种类、晶种数量、溶液体系中还原剂的浓度及硝酸银浓度 对银粉形貌和粒径的影响。结果表明：采用强还原剂制备的银粉团聚严重，粒径不均匀；当体系中还原剂浓度太 小(0.05 mol/L)或太大(0.25 mol/L)时，银粉粒径很小，团聚严重；当加入的晶种数量较少时(1 mL) ，银粉粒径不均 匀，而当晶种数量较大(3 mL)时，银粉粒径很小，团聚严重；随硝酸银的浓度从0.05 mol/L增加到0.20 mol/L，银 粉粒径先增大后减小。采用还原性较弱的抗坏血酸为还原剂，晶种体积为2 mL ，体系中C H O 和AgNO 的浓度 6 8 6 3 均为0.15 mol/L时，制备出表面光滑、分散性较好、粒径均匀、粒度为1.5 μm的球形银粉。 关键词：分步还原；抗坏血酸；球形银粉；化学还原 + 中图分类号：TF 123.7 3 文献标志码：A 文章编号：1673−0224(2016)01− 109−07 Morphology and particle size of micro spherical silver fabricated by multistep reduction LI Biyuan, GAN Weiping, LI Yingfen, ZHOU Jian, WANG Xiaoqing (School of Materials Science and Engineering, Central South University, Changsha 410083, China) Abstract: Sodium borohydride was used as reducer to prepare silver seed, and then the silver nitrate was reduced step-by-step in aqueous solution to fabricate micron silver powder. The effects of reducing agent, the amount of silver seed, the concentration of reducer and silver nitrate on the size and morphology of the silver particles were studied. SEM and X-ray diffracti