analysis of chloride content related to the seminar sa（分析sa氯化物含量相关研讨会）.docVIP

Analysis of chloride content related to the seminar Sa Abstract: At present, analytical methods are boiling and chemical analysis, but the first two methods have different drawbacks, which we changed to iodometric analysis. After the actual analysis and contrast compared with the previous two methods more accurate and feasible. Keywords: boiling, chemical; iodometric method 1 Introduction Boiling method is based on 75-80 `C distillate boiling ranges to determine the volume of thionyl chloride content, the method determined by the conditions and environmental factors, the analysis of large errors, the result is low. Chemical analysis, generally follow the alum chloride of sodium hydroxide aqueous solution hydrolysis, hydrochloric acid standard solution titration of excess sodium hydroxide, that is obtained alum chloride content. SOCl2 +4 NaOH = Na2S04 +2 NaCl +2 H20 NaOH (excess) + HCl = NaCl + H20 This approach also has drawbacks: the sample because of thionyl chloride chloride, sulfur monochloride, sulfur dichloride can react with sodium hydroxide to make the results of thionyl chloride content high. To this end the chloride sulfoxide to explore various methods of chemical analysis by the reaction control experiments, obtained using iodometric determination of thionyl chloride content method. (2) principle of the method Thionyl chloride and sodium chloride solution containing dilute hydrogen reaction of sodium sulfite with excess iodine will be oxidized to sodium sulfate sodium sulfite, and the remaining iodine titrated with sodium thiosulfate standard solution, using starch as indicator to determine the end point, but do blank test. SOC12 +4 NaOH = Na2SO3 +2 NaCl +2 H20 Na2SO3 + I2 + H2O = Na2S04 +2 HI I2 ten Na2S2O3 = Na2S04 +2 Nal Reagents and solutions: (1) iodine standard solution: C (1 / 2 I2) = 0.1mol / l (2) sodium thiosulfate standard solution C (Na2SO3) = 0.1mol / l (3) sodium hydroxide solution: