实验化学思考题(好孩子不要用噢)（Experimental chemistry thinking question (good boy, dont use it)）.docVIP

实验化学思考题(好孩子不要用噢)（Experimental chemistry thinking question (good boy, dont use it)） The determination of total acid in vinegar. Seven, think questions (questions) 1. no CO2 distilled water how to prepare, if diluted vinegar distilled water contains CO2, what effect on the results of the test, why? Answer: Boil the distilled water to remove the CO2.. If it contains CO2, it produces a positive error, that is, the volume of the titrated NaOH is on the high side, because the CO2 in distilled water also consumes a certain amount of NaOH standard solution 2. whether the pipettes and cones used in the titration are washed with vinegar solution? Why? Answer: pipette solution to rinse with vinegar, and vinegar rinse solution without the conical flask. Because the pipette solution if no vinegar rinse, then its inner wall covered with water, dilute will be tested vinegar solution, effects of titration results, negative error; and vinegar solution by a conical flask the pipette accurately removed, if the conical flask wash with vinegar solution run, vinegar droplets is attached on the inner wall of the titration results will make high. 3. could the methyl orange be used as indicator in the determination of vinegar content? Answer: No. because of methyl orange color range is 3.1 ~ 4.4, the acid range, while NaOH HAc titration, generation of stoichiometric point is NaAc, NaHCO3, weakly alkaline, can only use alkalescent color range indicator such as phenolphthalein, in order to make the end point error to a minimum. In experiment two, calibration and determination of hydrogen peroxide content of Potassium Permanganate Seven, think questions (questions) 1.H2O2 liquid label marked that the content is 30%, the experimental result is less than this value, why? Answer: because H2O2 is unstable, it releases oxygen easily, so its concentration drops, so the experimental result is less than 30% 2. why not direct removal solution were determined, and the sample is diluted to remove the sol