1,5-diaminopentane as a structure-directing agent for zincophosphate networks zn3(po4)2(c5h14n2)2·3h2o and c5h16n2·zn3(po4)2(hpo4)·h2o1,5-diaminopentane作为zincophosphate一类代理网络zn3(po4)2(c5h14n2)2·3 h2o和c5h16n2·zn3(po4)2 hpo4·h2o.pdfVIP

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1,5-diaminopentane as a structure-directing agent for zincophosphate networks zn3(po4)2(c5h14n2)2·3h2o and c5h16n2·zn3(po4)2(hpo4)·h2o1,5-diaminopentane作为zincophosphate一类代理网络zn3(po4)2(c5h14n2)2·3 h2o和c5h16n2·zn3(po4)2 hpo4·h2o.pdf

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1,5-diaminopentane as a structure-directing agent for zincophosphate networks zn3(po4)2(c5h14n2)2·3h2o and c5h16n2·zn3(po4)2(hpo4)·h2o1,5-diaminopentane作为zincophosphate一类代理网络zn3(po4)2(c5h14n2)2·3 h2o和c5h16n2·zn3(po4)2 hpo4·h2o

Crystals 2012, 2, 974-983; doi:10.3390/cryst2030974 OPEN ACCESS crystals ISSN 2073-4352 /journal/crystals Article 1,5-Diaminopentane As A Structure-Directing Agent for Zincophosphate Networks: Zn (PO ) (C H N ) ·3H O and 3 4 2 5 14 2 2 2 C H N ·Zn (PO ) (HPO )·H O 5 16 2 3 4 2 4 2 William T.A. Harrison * and William R. Currie Department of Chemistry, University of Aberdeen, Meston Walk, Aberdeen AB24 3UE, Scotland, UK; E-Mail: curriedbill@ * Author to whom correspondence should be addressed; E-Mail: w.harrison@abdn.ac.uk; Tel.: +44-1224-272897; Fax: +44-1224-272921. Received: 5 June 2012; in revised form: 28 June 2012 / Accepted: 3 July 2012 / Published: 16 July 2012 Abstract: The crystal structures of two zincophosphate networks prepared in the presence of 1,5-diaminopentane (dap) are described. In Zn (PO ) (C H N ) ·3H O (1) the dap 3 4 2 5 14 2 2 2 forms Zn–N coordinate bonds to generate an unusual three-dimensional “hybrid” framework constructed from ZnO N, ZnO N and PO tetrahedra with three different types 3 2 2 4 of elongated channels occupied by water molecules. In C H N ·Zn (PO ) (HPO )·H O; (2)