4-{[(4-methoxyphenyl)imino]methyl}-3-hydroxyphenyl 4-(hexadecanoyloxy)benzoate4 - {((4-methoxyphenyl)亚氨基的)甲基} 3-hydroxyphenyl 4 -(hexadecanoyloxy)苯甲酸.pdfVIP

4-{[(4-methoxyphenyl)imino]methyl}-3-hydroxyphenyl 4-(hexadecanoyloxy)benzoate4 - {((4-methoxyphenyl)亚氨基的)甲基} 3-hydroxyphenyl 4 -(hexadecanoyloxy)苯甲酸.pdf

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4-{[(4-methoxyphenyl)imino]methyl}-3-hydroxyphenyl 4-(hexadecanoyloxy)benzoate4 - {((4-methoxyphenyl)亚氨基的)甲基} 3-hydroxyphenyl 4 -(hexadecanoyloxy)苯甲酸

Molbank 2012, M753; doi:10.3390/M753 OPEN ACCESS molbank ISSN 1422-8599 /journal/molbank Short Note 4-{[(4-Methoxyphenyl)imino]methyl}-3-hydroxyphenyl 4- (Hexadecanoyloxy)benzoate Sie-Tiong Ha 1,*, Guan-Yeow Yeap 2 and Peng-Lim Boey 2 1 Department of Chemical Science, Faculty of Science, Universiti Tunku Abdul Rahman, Jln Universiti, Bandar Barat, 31900 Kampar, Perak, Malaysia 2 Liquid Crystal Research Laboratory, School of Chemical Sciences, Universiti Sains Malaysia, 11800 Minden, Penang, Malaysia * Author to whom correspondence should be addressed; E-Mails: hast_utar@ or hast@.my. Received: 27 February 2012 / Accepted: 9 April 2012 / Published: 17 April 2012 Abstract: A new Schiff base ester, 4- {[(4-methoxyphenyl)imino]methyl}-3-hydroxyphenyl 4-(hexadecanoyloxy)benzoate was synthesized and its IR, 1H NMR, 13C NMR and MS spectroscopic data are presented. Keywords: Schiff base; liquid crystal; 4- {[(4-methoxyphenyl)imino]methyl}-3- hydroxyphenyl 4-(hexadecanoyloxy)benzoate Much attention has been focused on Schiff base derivatives owing to their thermochromic and photochromic properties [1–5]. Schiff bases are also well recognized for their liquid crystal properties since the discovery of MBBA which exhibited room temperature nematic phase [6]. An appropriate length of the alkyl chain at the para position of the aldehyde or aniline fragment of N-benzylidene- anilines has also been identified as one of the main requirements which favours the existence of liquid crystal phase (or mesophase)

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