a review of recent advances on the effects of microstructural refinement and nano-catalytic additives on the hydrogen storage properties of metal and complex hydrides审查的最新进展的影响显微结构的细化和nano-catalytic添加剂的储氢性能的金属氢化物和复杂.pdfVIP

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a review of recent advances on the effects of microstructural refinement and nano-catalytic additives on the hydrogen storage properties of metal and complex hydrides审查的最新进展的影响显微结构的细化和nano-catalytic添加剂的储氢性能的金属氢化物和复杂.pdf

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a review of recent advances on the effects of microstructural refinement and nano-catalytic additives on the hydrogen storage properties of metal and complex hydrides审查的最新进展的影响显微结构的细化和nano-catalytic添加剂的储氢性能的金属氢化物和复杂

Energies 2011, 4, 1-25; doi:10.3390/en4010001 OPEN ACCESS energies ISSN 1996-1073 /journal/energies Review A Review of Recent Advances on the Effects of Microstructural Refinement and Nano-Catalytic Additives on the Hydrogen Storage Properties of Metal and Complex Hydrides Robert A. Varin 1,*, Leszek Zbroniec 1, Marek Polanski 2 and Jerzy Bystrzycki 2 1 Department of Mechanical and Mechatronics Engineering, University of Waterloo, Waterloo, Ontario, N2L 3G1, Canada; E-Mail: leszek.zbroniec@ 2 Faculty of Advanced Technology and Chemistry, Military University of Technology, 2 Kaliskiego Str., 00-908 Warsaw, Poland; E-Mails: mpolanski@.pl (M.P.); jbystrzycki@.pl (J.B.) * Author to whom correspondence should be addressed; E-Mail: ravarin@uwaterloo.ca; Tel.: + 1 519 888 4567; Fax: + 1 519 885 5862. Received: 11 November 2010; in revised form: 10 December 2010 / Accepted: 20 December 2010 / Published: 24 December 2010 Abstract: The recent advances on the effects of microstructural refinement and various nano-catalytic additives on the hydrogen storage properties of metal and complex hydrides obtained in the last few years in the allied laboratories at the University of Waterloo (Canada) and Military University of Technology (Warsaw, Poland) are critically reviewed in this paper. The research results indicate that microstructural refinement (particle and grain size) induced by ball milling influences quite modestly the hydrogen storage propertie