污水处理厂出水中氰化物测定方法及影响因素的分析.pdfVIP

sulfamic acid and then cyanide samples，then adding NaOH to improve pH,the samples can be removed the interferes effectively.Laboratory simulation wastewater results showed NO3- was the main interfering ion for cyanide derermination, it may due to NO3- can react with carbon - - and produce new CN .NO3 in the process of cyanide in sample pretreatment can cause results higher than the real cyanide concentration. Wastewater treatment plant experiments verified sample holding time, sample saved with or without headspace, preprocessing steps have influences on cyanide determination for final effluent.Samples having completely pretreated preserved with no headspace measure cyanide immediately ,the results can get closer to real value. Keywords : Cyanide; Selective electrode method; Micro distillation spectrophotometer method ；influencial factors Thesis : Application Research 万方数据 目 录 目 录 1 绪论 1 1.1 研究背景及意义 1 1.2 氰化物以及测定方法国内外研究进展 2 1.2.1 氰化物的种类 2 1.2.2 氰化物测定方法研究进展 3 1.3 氰化物测定影响因素研究进展 5 1.4 技术路线 8 1.5 研究内容 10 2 Wildcat Hill 污水处理厂监测数据分析 11 2.1 氨、硝酸盐和氰化物浓度监测数据分析 11 2.2 氨、硝酸盐和含碳物质浓度范围 14 2.3 本章小结 17 3 选择电极法测定氰化物浓度的影响因素研究 18 3.1 实验部分 18 3.1.1 实验药品和仪器 18 3.1.2 氰化物浓度测定值评价指标 18 3.1.3 实验内容 19 3.2 结果与讨论 20 - 3.2.1 CN 标准曲线 20 3.2.2 方法检出限的确定 22 3.2.3 样品保存时间对氰化物测定的影响 23 3.2.4 氯化消毒以及脱氯对氰化物测定的影响 24 3.2.5 样品保存瓶容积对氰化物测定影响 25 3.3 本章小结 27 4 微管分光光度法测定氰化物影响因素分析 28 4.1 实验部分 28