生物分离工程第六章的 离子交换与吸附.ppt

Chapter 6吸附与离子交换Adsorption and ion exchange;Knowledge points;什么是吸附？;常见的吸附类型及其主要特点;常见的吸附类型及其主要特点;常用吸附剂种类;活 性 炭（Active carbon）;粉末活性炭;锦纶活性炭;活性炭对物质的吸附规律;硅胶 层析用硅胶有多孔网状结构，优点：惰性，有较大吸附量。易制备不同类型、孔径、表面积的多孔性硅胶。分离范围广；缺点：难以工业化。 氧化铝 特点：亲水性吸收剂；较高的吸附容量；分离效果好；特别适用于亲脂性成分的分离；缺点：难以工业化。 ;大孔网状吸附剂(macroporous resin);大孔网状吸附树脂的种类;大孔吸附树脂的吸附机理;常用的解吸方法;吸附等温线; Irving Langmuir (31 Jan. 1881 – 16 Aug. 1957) was an American chemist and physicist. His most noted publication was the famous 1919 article The Arrangement of Electrons in Atoms and Molecules in which, building on Gilbert N. Lewiss cubical atom theory and Walther Kossels chemical bonding theory, he outlined his concentric theory of atomic structure. Langmuir became embroiled in a priority dispute with Lewis over this work; Langmuirs presentation skills were largely responsible for the popularization of the theory, although the credit for the theory itself belongs mostly to Lewis. While at General Electric (GE company), from 1909–1950, Langmuir advanced several basic fields of physics and chemistry, invented the gas-filled incandescent lamp, the hydrogen welding technique, and was awarded the 1932 Nobel Prize in Chemistry for his work in surface chemistry. He was the first industrial chemist to become a Nobel laureate. The Langmuir Laboratory for Atmospheric Research near Socorro, New Mexico was named in his honor as was the American Chemical Society journal for Surface Science, called Langmuir.;Langmuir吸附等温线;影响吸附的主要因素;什么是亲和吸附？(Affinity adsorption);Affinity adsorption;亲和吸附的特点;亲和吸附载体的种类;载体的活化和偶联;例如：载体活化中的环氧化法;配基偶联方法;影响亲和吸附的因素;常用的吸附单元操作方式;离子交换(ion exchange) ;离子交换树脂的结构;树脂的网络骨架（类似于大孔树脂）;离子交换树脂三维空间立体结构;离子交换的分类;离子交换的一般过程;常用的离子交换树脂;新型离子交换树脂;大孔离子交换树脂的优点;其它离子交换树脂类型;主要的多糖基离子交换树脂;葡聚糖凝胶离子交换树脂 骨架为葡聚糖凝胶，如sepharose、sephadex，根据功能基团的不同，亦可分为阳离子交换和阴离子交换树脂 命名方法：交换活性基团+骨架+原骨架编号 特点：除了具有离子交换功能以外，兼有分子筛的功能，提高了分离的效率 常用的葡聚糖凝胶离子交换树脂：CM-sephadex C-25、DEAE-sephadex A-25等;DEAE anion exchanger;CMC Cation Exchanger;Evaluation only. Created with Aspose.Slides