磷酸钙盐在蚕丝纤维上的沉积矿化-苏州大学纺织服装试验教学示范中心.PDF

第 27 卷 　第 11 期 纺 　织 　学 　报 Vol . 27 　No . 11 2006 年 11 月 Journal of Textile Research Nov. 　2006 ( ) 文章编号 2006 磷酸钙盐在蚕丝纤维上的沉积矿化 卢神州 , 李明忠 , 黄玲萍 , 白伦 (苏州大学 材料工程学院 ,江苏 苏州 　215021) 摘 　要 　将脱胶蚕丝纤维分别浸渍在磷酸氢二钠和硝酸钙溶液中矿化 ,使磷酸钙盐沉积在蚕丝纤维上 。采用 X 射线 衍射仪分析了沉积物的结构 ,结果显示沉积在蚕丝纤维上的结晶主要为羟基磷灰石晶体 ;扫描电子显微镜观察显示 沉积物呈鳞片状及针状结晶;拉伸强度测试结果显示纤维矿化以后发硬 ,拉伸断裂伸长率下降 ,拉伸断裂强度也下 降 ,总体变化不明显 。磷酸钙盐与蚕丝纤维有较好的亲和力 ,能在蚕丝纤维上沉积 ,而对纤维的性能影响不大 。 关键词 　蚕丝纤维 ; 磷酸钙 ; 矿化 ; 性能 中图分类号 :TS10192 　　　文献标识码 :A 　　　 Sediment and mineralization of calcium phosphate on the silk f iber LU Shenzhou , L I Mingzhong , HUAN G Lingping , BAI Lun ( Schoot of M aterial Engineering , Soochow University , S uzhou ,J iangsu 　215021 , China) Abstract 　The degummed silk fibers were treated with disodium hydrogen phosphate and calcium nitrate solutions respectively by immersion method for mineralization so that the calcium phosphate could deposit on silk fibers. The sediment state of calcium phosphate on silk fibers was investigated by SEM , and the structure of the sediment was analyzed by XRD . The results showed that the sediments on silk fibers were mainly scale like and needlelike hydroxyapatite crystals. Tensile strength testing of the mineralized fibers indicated that they became harder and their breaking extension and strength decreased , but the changes were not distinct . The calcium phosphate has good affinity to silk fibers , can deposit on them with little effect on their properties. Key words 　silk fiber ; calcium phosphate ; mineralization ; property 　　硬组织修复材料