diphenyl(2-propoxyethyl)phosphine二苯(2-propoxyethyl)磷化氢.pdfVIP

Molbank 2010, M709; doi:10.3390/M709 OPEN ACCESS molbank ISSN 1422-8599 /journal/molbank Short Note Diphenyl(2-propoxyethyl)phosphine Mohammed Al-Nuri Chemistry Department, AN-Najah National University, P.O. Box 7, Nablus, Palestine; E-Mail: mohammed.alnuri@ Received: 15 October 2010 / Accepted: 26 November 2010 / Published: 2 December 2010 Abstract: A new 2-(diphenylphosphino)ethyl propyl ether as hemilabile hybrid ether- phosphine ligand [Ph PCH CH OCH CH CH ] was made available. The structure of the 2 2 2 2 2 3 31 1 titled compound was characterized by elemental analysis, IR, P-NMR, H-NMR, 13C-NMR, UV-visible spectroscopy and EI-MS. 31 Keywords: ether-phosphine; bifunctional ligand; P-NMR 1. Introduction In recent years, there has been a considerable interest in the design and use of so-called hemilabile ligands [1-5]. They contain a soft donor (e.g., phosphorus) closely coordinated to the transition metal with a hard donor (e.g., oxygen) forming only a weak contact to the metal center. Due to this feature, the (ether) oxygen atom can easily be displaced by an incoming substrate. In addition, the oxygen function, which may be regarded as an intramolecular solvent, is able to stabilize a transitio