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phase diagrams for systems containing hyperbranched polymers相图系统含有超支化聚合物
Polymers 2012, 4, 72-115; doi:10.3390/polym4010072
OPEN ACCESS
polymers
ISSN 2073-4360
/journal/polymers
Review
Phase Diagrams for Systems Containing Hyperbranched Polymers
Sabine Enders 1,*, Kai Langenbach 1, Philipp Schrader 1 and Tim Zeiner 2
1 TU Berlin, Fachgebiet Thermodynamik und Thermische Verfahrenstechnik, Sekr. BH 7-1,
Ernst-Reuter-Platz 1, D-10587 Berlin, Germany; E-Mails: Kai.Langenbach@tu-berlin.de (K.L.);
p.schrader@tu-berlin.de (P.S.)
2 TU Dortmund, Lehrstuhl Fluidverfahrenstechnik, Emil-Figge-Str. 70, D-44227 Dortmund,
Germany; E-Mail: Tim.Zeiner@bci.tu-dortmund.de
* Author to whom correspondence should be addressed; E-Mail: Sabine.Enders@tu-berlin.de;
Tel.: +49-30-314-227-55; Fax: +49-30-314-224-06.
Received: 2 November 2011; in revised form: 15 December 2011 / Accepted: 4 January 2012 /
Published: 9 January 2012
Abstract: Hyperbranched polymers show an outstanding potential for applications ranging
from chemistry over nanotechnology to pharmacy. In order to take advantage of this
potential, the underlying phase behaviour must be known. From the thermodynamic point
of view, the modelling of these phase diagrams is quite challenging, because the
thermodynamic properties depend on the architecture of the hyperbranched polymer as
well as on the number and kind of present functional end groups. The influence of
architecture can be taken into account via the lattice cluster theory (LCT) as an extension
of the well-known
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