photoelectrode characteristics of partially hydrolyzed aluminum phthalocyanine chloridefullerene c60 composite nanoparticles working in a water phase光电极的特点,部分水解铝酞菁chloridefullerene c60复合纳米粒子在水相.pdfVIP

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photoelectrode characteristics of partially hydrolyzed aluminum phthalocyanine chloridefullerene c60 composite nanoparticles working in a water phase光电极的特点,部分水解铝酞菁chloridefullerene c60复合纳米粒子在水相.pdf

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photoelectrode characteristics of partially hydrolyzed aluminum phthalocyanine chloridefullerene c60 composite nanoparticles working in a water phase光电极的特点,部分水解铝酞菁chloridefullerene c60复合纳米粒子在水相

Molecules 2012, 17, 10801-10815; doi:10.3390/molecules170910801 OPEN ACCESS molecules ISSN 1420-3049 /journal/molecules Article Photoelectrode Characteristics of Partially Hydrolyzed Aluminum Phthalocyanine Chloride/Fullerene C60 Composite Nanoparticles Working in a Water Phase Shuai Zhang 1,2, Toshiyuki Abe 3, Tomokazu Iyoda 1 and Keiji Nagai 1,* 1 Chemical Resources Laboratory, Division of Integrated Molecular Engineering, Tokyo Institute of Technology, Yokohama 226-8503, Japan; E-Mails: shuaizhang@ (S.Z.); iyoda.t.aa@m.titech.ac.jp (T.I.) 2 Center for Low-Dimensional Materials, Micro-Nano Devices and System, Changzhou University, Changzhou 213164, Jiangsu, China 3 Department of Frontier Materials Chemistry, Graduate School of Science and Technology, Hirosaki University, 3 Bunkyo-cho, Hirosaki, Aomori 036-8561, Japan; E-Mail: tabe@cc.hirosaki-u.ac.jp * Author to whom correspondence should be addressed; E-Mail: nagai.k.ae@m.titech.ac.jp; Tel.: +81-45-924-5266; Fax: +81-45-924-5247. Received: 25 July 2012; in revised form: 28 August 2012 / Accepted: 5 September 2012 / Published: 10 September 2012 Abstract: Photoelectrochemical measurements were used to study the photoelectrode characteristics of composite nanoparticles composed of fullerene C60 and partially hydrolyzed aluminum phthalocyanine chloride (AlPc). In cyclic voltammetry measurements, the electrodes coated with the composite nanoparticles were found to have photoanodic [electron donor: 2-mercaptoethanol (ME)] and