原创力文档respiratory monitoring by porphyrin modified quartz crystal microbalance sensors呼吸监测由卟啉改性石英晶体微量天平传感器.pdfVIP
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respiratory monitoring by porphyrin modified quartz crystal microbalance sensors呼吸监测由卟啉改性石英晶体微量天平传感器
Sensors 2011, 11, 1177-1191; doi:10.3390/s110101177
OPEN ACCESS
sensors
ISSN 1424-8220
/journal/sensors
Article
Respiratory Monitoring by Porphyrin Modified Quartz Crystal
Microbalance Sensors
Roman Selyanchyn 1, Serhiy Korposh 1, Shunichi Wakamatsu 2 and Seung-Woo Lee 1,*
1 Graduate School of Environmental Engineering, The University of Kitakyushu, 1-1 Hibikino,
Wakamatsu, Kitakyushu 808-0135, Japan; E-Mails: romanselyanchyn@ (R.S.);
s-korposh@env.kitakyu-u.ac.jp (S.K.)
2 Chitose Technical Center, Nihon Dempa Kogyo Co. Ltd., 1-3-1, Minami-Chitose,
Hokkaido 066-0009, Japan; E-Mail: wakamatu@
* Author to whom correspondence should be addressed; E-Mail: leesw@env.kitakyu-u.ac.jp;
Tel.: +81-93-695-3293; Fax: +81-93-695-3384.
Received: 1 December 2010; in revised form: 30 December 2010 / Accepted: 10 January 2011 /
Published: 20 January 2011
Abstract: A respiratory monitoring system based on a quartz crystal microbalance (QCM)
sensor with a functional film was designed and investigated. Porphyrins
5,10,15,20-tetrakis-(4-sulfophenyl)-21H,23H-porphine (TSPP) and 5,10,15,20-tetrakis-(4-
sulfophenyl)-21H, 23H-porphine manganese (III) chloride (MnTSPP) used as sensitive
elements were assembled with a poly(diallyldimethyl ammonium chloride) (PDDA). Films
were deposited on the QCM resonators using layer-by-layer method in order to develop the
sensor. The developed system, in which the sensor response reflects lung movements, was
able to track human respiration providing re
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