原创力文档superparamagnetic nanocomposites templated with pyrazole-containing diblock copolymers超顺磁的纳米复合材料模板化与pyrazole-containing diblock共聚物.pdfVIP
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superparamagnetic nanocomposites templated with pyrazole-containing diblock copolymers超顺磁的纳米复合材料模板化与pyrazole-containing diblock共聚物
Polymers 2012, 4, 1211-1225; doi:10.3390/polym4021211
OPEN ACCESS
Polymers
ISSN 2073-4360
/journal/polymers
Article
Superparamagnetic Nanocomposites Templated with
Pyrazole-Containing Diblock Copolymers
Sanchita Biswas 1, Kevin D. Belfield 1,*, Ritesh K. Das 2, Siddhartha Ghosh 2
2
and Arthur F. Hebard
1 Department of Chemistry, University of Central Florida, P.O. Box 162366, Orlando,
FL 32816, USA; E-Mail: sbiswas@
2 Department of Physics, University of Florida, Gainesville, FL 32611, USA;
E-Mails: rkdas@ (R.K.D.); ghoshsi@ (S.G.); afh@ (A.F.H.)
* Author to whom correspondence should be addressed; E-Mail: belfield@;
Tel.: +1-407-823-1028; Fax: +1-407-823-2252.
Received: 19 March 2012; in revised form: 26 April 2012 / Accepted: 14 May 2012 /
Published: 31 May 2012
Abstract: Monodisperse maghemite nanoparticles, templated in novel, well-defined
pyrazole-containing norbornene-based block copolymers, provided a superparamagnetic
nanocomposite with high saturation magnetization at room temperature under an applied
magnetic field. The synthesis of the polymer nanocomposites and physical, morphological,
and magnetic chracaterization of the nanocomposites are reported. Micelle-encapsulated
superparamagnetic nanocomposites were generated for dispersal in aqueous medium. Their
stability in water in the presence of a magnetic field was investigated as was their
morphology and cell viability, strongly suggesting the potential of these superpar
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