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synthesis and polymerizability of atom-bridged bicyclic monomers的合成和聚合性atom-bridged二环的单体.pdf

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synthesis and polymerizability of atom-bridged bicyclic monomers的合成和聚合性atom-bridged二环的单体

Polymers 2012, 4, 1674-1686; doi:10.3390/polym4041674 OPEN ACCESS polymers ISSN 2073-4360 /journal/polymers Review Synthesis and Polymerizability of Atom-Bridged Bicyclic Monomers Henry K. Hall, Jr. Department of Chemistry and Biochemistry, University of Arizona, 1306 E University Blvd, Tucson, AZ 85721, USA; E-Mail: hkh@; Tel.: +1-520-621-6326; Fax: +1-520-621-8407 Received: 11 September 2012; in revised form: 19 November 2012 / Accepted: 20 November 2012 / Published: 5 December 2012 Abstract: The synthesis and polymerizability of atom-bridged bicyclic monomers was surveyed. The monomers included lactams, ureas, urethanes, lactones, carbonates, ethers, acetals, orthoesters, and amines. Despite widely-varying structures, they almost all polymerized to give polymers with monocyclic rings in the chain. The polymerizations are grouped by mechanism: uncoordinated anionic, coordinated anionic, and cationic. Keywords: alicyclic ring-containing polymers; anti-Bredt monomers; atom-bridged bicyclic monomers; ring-opening polymerizations 1. Introduction Ring-opening polymerizations, which convert cyclic monomers into linear polymers, are a major type of polymerization. A recent authoritative treatise [1] covered ring-opening polymerization of monocyclic monomers; this Review covers ring-opening polymerization of atom-bridged bicyclic monomers. “Atom-bridged” means all three chains connecting the bridgehead atoms contain at least one atom. Bicyclic compounds with bridgehe