synthesis and properties of acyclic ammonium-based ionic liquids with allyl substituents as electrolytes无环的合成和性质与取代基烯丙基氨离子液体电解质.pdfVIP

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synthesis and properties of acyclic ammonium-based ionic liquids with allyl substituents as electrolytes无环的合成和性质与取代基烯丙基氨离子液体电解质.pdf

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synthesis and properties of acyclic ammonium-based ionic liquids with allyl substituents as electrolytes无环的合成和性质与取代基烯丙基氨离子液体电解质

Molecules 2009, 14, 1840-1851; doi:10.3390/molecule OPEN ACCESS molecules ISSN 1420-3049 /journal/molecules Article Synthesis and Properties of Acyclic Ammonium-based Ionic Liquids with Allyl Substituents as Electrolytes Taeeun Yim, Chang Young Choi, Junyoung Mun, Seung M. Oh * and Young Gyu Kim * Department of Chemical and Biological Engineering, Research Center for Energy Conversion Storage, Seoul National University, Seoul 151-744, Korea; E-mails: yte0102@snu.ac.kr (T.Y.), max923@snu.ac.kr (C-Y.C.), river7@snu.ac.kr (J.M.) * Author to whom correspondence should be addressed; E-mails: seungoh@plaza.snu.ac.kr (S-M.O.) or ygkim@snu.ac.kr (Y-G.K.); Tel.: 82-2-880-8347; Fax: 82-2-885-6989 Received: 18 April 2009; in revised form: 12 May 2009 / Accepted: 13 May 2009 / Published: 15 May 2009 Abstract: Several new acyclic ammonium-TFSI ionic liquids with an allyl substituent(s) were synthesized and their physicochemical and electrochemical properties were characterized. [AAMM]Am-TFSI (3) with two allyl groups showed the widest electrochemical stability window (5.9 V) among the ammonium-based ILs reported to date because of the increment of both the anodic and cathodic limits. The charge-discharge performance of a LiCoO -based half-cell containing [AAMM]Am-TFSI as an electrolyte 2 was better in cycleability (the capacity retention ratio: 99% after 20 cycles) than that of the cell with the corresponding partially saturated an