the adsorption of n-octanohydroxamate collector on cu and fe oxide minerals investigated by static secondary ion mass spectrometryn-octanohydroxamate收集器的吸附铜和铁氧化物矿物调查静态二次离子质谱分析.pdfVIP

Minerals 2012, 2, 493-515; doi:10.3390/min2040493 OPEN ACCESS minerals ISSN 2075-163X /journal/minerals Article The Adsorption of n-Octanohydroxamate Collector on Cu and Fe Oxide Minerals Investigated by Static Secondary Ion Mass Spectrometry Alan N. Buckley 1,*, John A. Denman 2 and Gregory A. Hope 3 1 School of Chemistry, University of New South Wales, Sydney, NSW 2052, Australia 2 Ian Wark Research Institute, University of South Australia, Mawson Lakes, SA 5046, Australia; E-Mail: John.Denman@.au 3 Queensland Micro- and Nanotechnology Centre, School of Biomolecular and Physical Sciences, Griffith University, Nathan, QLD 4111, Australia; E-Mail: g.hope@.au * Author to whom correspondence should be addressed; E-Mail: a.buckley@.au; Tel.: +61-2-9385-4677; Fax: +61-2-9662-1697. Received: 12 September 2012; in revised form: 26 November 2012 / Accepted: 4 December 2012 / Published: 10 December 2012 Abstract: The feasibility of investigating the adsorption of n-octanohydroxamate collector on copper and iron oxide minerals with static secondary ion mass spectrometry has been assessed. Secondary ion mass spectra were determined for abraded surfaces of air-exposed copper metal, malachite, pseudomalachite and magnetite that had been conditioned in aqueous potassium hydrogen n-octanohydroxamate solution, as well as for the corresponding bulk CuII and FeIII complexes. In each case, the chemical species present at the solid/vacuum interface of a similarly prepared surface were established by X-ray photoelectron spectroscopy. The most