the electrochemical detremination of nitric oxide in seawater media with microelectrodes海水中的一氧化氮电化学detremination媒体与微电极.pdfVIP

Sensors 2003, 3, 304-313 sensors ISSN 1424-8220 2003 by MDPI /sensors The Electrochemical Detremination of Nitric Oxide in Seawater Media with Microelectrodes 1,2* 1 2 2 1 Zhengbin Zhang , Lei Xing , Liqing Jiang , Yongchen Wang , Chunyan Ren and Wei-Jun 2** Cai 1 Institute of Marine Chemistry, Ocean University of China, Qingdao 266003, China, e-mail: zhangzb @; Fax: +86-532-2032483 2 Department of Marine Science, the University of Georgia, Athens, GA 30602, USA ** wcai @; Tel: 706-542-1285 * Authors to whom correspondence should be addressed. Received: 15 Ap ril 2003 / Accep ted: 02 May 2003 / Published: 22 A ugust 2003 Abstract: The electrochemical determination of nitric oxide in seawater with microelectrodes is reported in this paper. Two electrodes, ISO-NOPMC microsensor and modified platinum microelectrode, are evaluated for their performance in seawater. The -6 -5 peak current is found to be linear with the NO concentration in the range 1×10 -1.2×10 -8 mol/l for both microelectrodes. The detection limit of ISO-NOPMC microsensor is 1.4×10 mol/l. Two methods for calibration of NO sensor, saturated NO solutions and d