vibrational stark effect of the electric-field reporter 4-mercaptobenzonitrile as a tool for investigating electrostatics at electrodesamsolution interfaces振动的斯塔克效应电场记者4-mercaptobenzonitrile作为调查工具静电学在electrodesamsolution接口.pdfVIP

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vibrational stark effect of the electric-field reporter 4-mercaptobenzonitrile as a tool for investigating electrostatics at electrodesamsolution interfaces振动的斯塔克效应电场记者4-mercaptobenzonitrile作为调查工具静电学在electrodesamsolution接口.pdf

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vibrational stark effect of the electric-field reporter 4-mercaptobenzonitrile as a tool for investigating electrostatics at electrodesamsolution interfaces振动的斯塔克效应电场记者4-mercaptobenzonitrile作为调查工具静电学在electrodesamsolution接口

Int. J. Mol. Sci. 2012, 13, 7466-7482; doi:10.3390/ijm OPEN ACCESS International Journal of Molecular Sciences ISSN 1422-0067 /journal/ijms Article Vibrational Stark Effect of the Electric-Field Reporter 4-Mercaptobenzonitrile as a Tool for Investigating Electrostatics at Electrode/SAM/Solution Interfaces Gal Schkolnik 1, Johannes Salewski 1, Diego Millo 1,2, Ingo Zebger 1, Stefan Franzen 3 and Peter Hildebrandt 1,* 1 Technische Universität Berlin, Insitut für Chemie, Sekr. PC14, Straße des 17, Juni 135, Berlin, D-10623, Germany; E-Mails: gal.schkolnik@mail.tu-berlin.de (G.S.); johannes.salewski@tu-berlin.de (J.S.); lo@vu.nl (D.M.); ingo.zebger@tu-berlin.de (I.Z.) 2 Biomolecular Spectroscopy, LaserLaB Amsterdam, Vrije Universiteit Amsterdam, De Boelelaan 1083, Amsterdam, NL-1081 HV, The Netherlands 3 Department of Chemistry, North Carolina State University, Box 8204, Raleigh, NC 27695, USA; E-Mail: stefan_franzen@ * Author to whom correspondence should be addressed; E-Mail: hildebrandt@chem.tu-berlin.de; Tel.: +49-0-30-314-21433; Fax: +49-0-30-314-21122. Received: 9 May 2012; in revised form: 6 June 2012 / Accepted: 11 June 2012 / Published: 18 June 2012 Abstract: 4-mercaptobenzonitrile (MBN) in self-assembled monolayers (SAMs) on Au and Ag electrodes was studied by surface enhanced infrared absorption and Raman spectroscopy, to correlate the nitrile stretching frequency with the local electric field