无机化学实验试题(Inorganic chemistry experiment questions).doc

无机化学实验试题(Inorganic chemistry experiment questions).doc

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无机化学实验试题(Inorganic chemistry experiment questions)

无机化学实验试题(Inorganic chemistry experiment questions) 1页 无机化学实验试题 答案参考 一完成并配平下列反应方程式或离子反应式(20分)。 错1题扣4分(物质错扣2分,配平错扣2分) 1。向KI溶液中滴加FeCl3溶液 3 + 2 + 2铁+ 2我=2铁+ I2 2。向Hg(NO)溶液中滴加SnCl溶液 3 2 2 2 + 2 + + 4 + 2汞+锡+ 2氯汞=CL +锡 2 2 Cl-离子=汞Hg 2 + Sn4 + 2氯1个即可答 2 2 3。向碘水溶液中滴加少量Na S O溶液 2 2 3 2 - 2—— 2 S O + O + 2我的我= 2 3 2 4 6 4. to the Potassium Permanganate solution of acid added in sodium sulfite solution - 2- + 2+ 2- 2 MnO + 5 SO + 6 H = 2 Mn + 5 SO + 3 H O 4342 5.KMnO decomposition by heating Four 2 KMnO = K, MnO + MnO + O 42422 Two. The experimental phenomena and corresponding products (30 points) of the following reactions are given Every day 5 points: the phenomenon of 3 points, 2 points of product 6. add NaOH solution to the CrCl solution until excess Three NaOH is not excessive, gray blue precipitate Cr (OH) 3 NaOH excessive green solution Cr (OH) 4- 7. to the mixed solution of ferric chloride and potassium thiocyanate in adding an excess of ammonium fluoride solution Before adding ammonium fluoride, red solution Fe (SCN) 2+ After adding ammonium fluoride, colorless solution FeF52- 8. add sodium sulfite solution to starch potassium iodate solution until excess Sodium sulfite is not excessive, blue I2 Sodium sulfite excess colorless I- 9. add FeSO solution to acidic K, Cr, O solution 4227 Green solution Cr3+ 10. to the mercuric nitrate solution dropping until excess potassium iodide solution Potassium iodide is not excessive, red precipitate HgI2 Excess potassium iodide, colorless solution, HgI42- 11. add sulfuric acid into the K Cr O solution and then add hydrogen peroxide 227 After the blue CrO5 is placed, the blue is broken into a light green Cr3+ One Page and 2 Three. Fill in the blanks (20 points) 12., CrCl 6H O crystal dissolved in a small amount of water after green solution. Heat the solution for a period 32 After cooling, the solution becomes blue purple. 4 points 13. adding ammonia to the HgCl solution produces precipitation of HgNH Cl. Add to the HgCl solution 2

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