甲醇气氛静态呼吸图法制备蜂窝状有序多孔膜Fabricationof.PDF

2012 年第70 卷 化 学 学 报 Vol. 70, 2012 第1 期, 45～50 ACTA CHIMICA SINICA No. 1, 45～50 ·研究论文· 甲醇气氛静态呼吸图法制备蜂窝状有序多孔膜 兰 平*,a 李 剑b 龚剑亮b 李 磊*,b (a 嘉兴学院高分子系 嘉兴 314001) (b 厦门大学材料学院 厦门 361005) 摘要 以原子转移自由基聚合方法合成的聚二甲基硅氧烷-b-聚苯乙烯(PDMS-b-PS)为铸膜材料, 在静态呼吸图的基础 上, 首次在甲醇氛围下利用PDMS-b-PS 的二硫化碳溶液铸膜得到了高度规整的蜂窝状有序多孔结构. 研究了聚合物溶 液浓度对孔径的影响, 并与水蒸汽氛围制备的孔结构进行了比较. 结果表明, 甲醇气氛下制备的多孔膜的孔径比水蒸 汽氛围下的大, 且孔的断面形貌呈“U ”形; 孔径随着溶液浓度的增大而减小. 该研究有利于呼吸图法制备有序结构材 料技术的进一步发展, 有助于人们更加准确与全面地认识呼吸图机理. 关键词 静态呼吸图; 嵌段共聚物; 蜂窝状结构 Fabrication of Honeycomb Polymeric Films via Breath-figure Process under Methanol Atmosphere Lan, Ping*,a Li, Jianb Gong, Jianliangb Li, Lei*,b a ( Institute of Polymer Material Engineering, Jiaxing University, Jiaxing 314001) (b College of Materials, Xiamen University , Xiamen 361005 ) Abstract In this paper, highly ordered honeycomb polymeric films were prepared via a static breath-figure process under methanol atmosphere for the first time. The employed block copolymer, poly(dimethylsiloxane)-block-polystyrene (PDMS-b-PS), was synthesized by atom transfer radical polym- erization. The influences of vapor atmosphere and the concentration of polymer solution on the morphology of the porous films were also investigated. Versus the morphologies of honeycomb polymer films fabricated