中国南方森林黄壤的铝活化模式.PDFVIP

30 7 Vol. 30, No. 7 2009 7 Jul. , 2009 ENVIRONMENTAL SCIENCE , , * ( , 100084) : , . 4 , , . , , pH 4 , pK = - 240 a = 165( ) pK = - 282a = 166( ) . , . , pH 4 , pAl pH , . : ; ; ; : X5 17 : A : 2009) Aluminum Mobilization Models of Forest Yellow Earth in South China XIN Yan, ZHAO Yu, DUAN Le ( Department of Env ronmental Sc ence and Eng neer ng, Ts nghua Un vers ty, Be j ng 100084, Ch na) Abstract: For the appl cat on of ac d f cat on models n pred ct ng eff ects of ac d depos t on and formulat ng control strategy n Ch na, t s mportant select ng reg onally appl cable models of so l alum num mob l zat on and determ n ng the r parameters. Based on the longterm mon tor ng results of so l water chem stry from four forested w atersheds n South Ch na, the appl cab l ty of a range of equ l br ums descr b ng alum num mob l zat on w as evaluated. The tested equ l br ums ncluded those for g bbs te, jurban te, kaol n te, mogol te, and SOMAl. Results show that the g bbs te equ l br um commonly used n several ac d f cat on models s not su table for the typ cal forest so l n South Ch na, wh le the mod f ed emp r cal g bbs te equat on s appl cable w th pK = - 240, a = 165 ( for upper layer) and pK = - 282 , a = 166 ( for low er layers) at only pH 4 . Compar ng w th the emp r cal g bbs te equat on , the other equ l br um s do not perform better. It can also be seen that pAl var es sl ghtly w th pH decreases at pH 4 , w h ch s unexpla nable by any of these suggested equ l br ums . Key words: alum num mob l zat on ; g bbs te; d ssolut on equ l br um ; so l ac d f cat on , , . , , . , , , , , . [ 1]