红外谱图的解析经验（Analytic experience of infrared spectrum）.docVIP

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红外谱图的解析经验（Analytic experience of infrared spectrum）.doc

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红外谱图的解析经验（Analytic experience of infrared spectrum）

红外谱图的解析经验（Analytic experience of infrared spectrum） Analytic experience of infrared spectrum The characteristic absorption of functional groups should be memorized by heart, because the characteristic absorption of functional groups is the basis of analytic spectrogram. An infrared spectrum of a hand that has been taken: (1) first of all, according to the spectrum, the carbon framework type is derived: the formula of unsaturation is calculated according to the formula: Unsaturation = F+1+ (T-O) /2, in which: F: valence atomic number 4 valence (C atoms), T: valence atomic number 3 valence (N atoms), O: the number of atoms of 1 valence valence (H atoms), When I was an undergraduate introduction to spectroscopy, the teacher gave me the formula, but the letters were changed by me: F, T, O, 4,3, 1, so that I wouldnt forget. For example, for example, benzene: C6H6, unsaturation = 6+1+ (0-6), /2 = 4, 3 double bonds, plus a ring, just right For 4 degrees of unsaturation; (2) analysis of C-H stretching vibration absorption in 3300~2800cm^-1 region; 3000 cm^-1 boundary: higher than 3000cm^-1; no Saturated carbon C-H stretching vibration absorption, there may be alkene, alkyne, aromatic compounds, while less than 3000cm^-1, usually full And C-H stretching vibration absorption; (3) if the absorption is slightly higher than 3000cm^-1, the elongation of the unsaturated carbon carbon bond should be analyzed in the 2250~1450cm^-1 frequency region Absorption characteristic peaks of contraction vibration: Alkyne 2200~2100 cm^-1 Ene 1680~1640 cm^-1 Aromatic ring 1600158015001450 cm^-1 If it has been identified as an alkene or an aromatic compound, the fingerprint region should be further resolved, i.e., the frequency region of the 1000~650cm^-1 Determine the number and location of the substituent (CIS, trans, adjacent, inter -, opposite); (4) carbon skeleton type determination, and then based on other functional groups, such as C=O, O-H, C-N and other characteristics of absorption to