三元材料LiNiCoMnO2的包覆改性研究进展.pdfVIP

三元材料Li[Ni-Co-Mn]O2 的包覆改性研究进展* * 崔妍，徐盛明 ，陈靖 （清华大学核能与新能源技术研究院, 北京, 100084 ） 摘要：近来，三元层状结构的Li[Ni-Co-Mn]O2 锂离子电池正极材料由于其高的放电容量，良好的安全性能 以及毒性小等优点成为当今研究的热点。它结合了LiCoO2 优良的循环性能，LiNiO2 高的放电容量以及 LiMnO2 优异的安全性能而成为最有前途的高能量密度混合动力汽车用锂离子电池正极材料。但是 Li[Ni-Co-Mn]O2 作为锂离子电池正极材料，还需要改善其循环性能，尤其是高充电截止电压和高倍率下的 充放电性能有待进一步提高。对Li[Ni-Co-Mn]O2 三元材料进行表面包覆改性可阻止电极材料与电解液的直 接接触，抑制循环过程中 HF 对电极材料的腐蚀，减少了电解液与电极材料的副反应，降低了电池在充放 电过程中的电荷转移电阻，从而进一步提高材料的高倍率电化学性能。本文主要讨论了碳包覆以及氧化物 包覆Li[Ni-Co-Mn]O2 三元材料的研究进展。 关键词：Li[Ni-Co-Mn]O2 三元材料；碳包覆；氧化物包覆；电化学性能 中图分类号：TM911 文献标识码：B The coating properties of the mixed Li[Ni-Co-Mn]O2 materials Cui Yan, Xu Shengming, Chen Jing (Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing, 100084) Abstract ：Recently, layered Li[Ni-Co-Mn]O transition metal mixed oxides bec ome the research 2 focus of cathode materials for lithium ion batteries due to their higher capacity, better safety and less toxicity. The mixed oxides inherit the merits of mono metal oxide such as good cyclability of LiCoO , high capacity delivery of LiNiO , and super safety of LiMnO , which make them the 2 2 2 promising candidates for the cathodes of advanced lithium batteries for use in high energy as required for hybrid electric vehicles (HEVs). However, the cycle performances of the Li[Ni-Co-Mn]O material as a lithium ion battery cathode need to be improved, especially charged 2 to higher voltage or discharged at higher rates. It is confirmed that the coated layer can prevent the direct contac