基于MOF封装的随机激光器.pdfVIP

www.advmat.de www.MaterialsV N Wavelength-Tunable Microlasers Based on the Encapsulation O I T of Organic Dye in Metal–Organic Frameworks A C I N Yanhui Wei, Haiyun Dong, Cong Wei, Wei Zhang, Yongli Yan, and Yong Sheng Zhao* U M M O Wavelength-tunable microlasers have attracted extensive atten- and facilitates the population transfer from the LE to the ICT C tion for their important roles in on-chip optical communica- state. This is helpful in building an effective laser level system tion, laser display, and chemical sensing,[ 1 ] but are challenging comprising two gain states. The ICT dye@MOF microlasers to achieve due to the limited bandwidth of most optical gain became controllable through the introduction of guest solvents materials.[ 2 ] In contrast, organic gain materials, with broad with different polarities, which was subsequently utilized to bandwidth, provide the possibility of modulating the gain build stable and wide-wavelength-tunable microlasers. The region in a large range.[ 3 ] As a typical example, intramolecular results offer a comprehensive understanding for the construc- charge transfer (ICT) dye molecules exhibit peculiar multiple tion of stable and tunable lasers in confi ned systems, and pro- excited states, including locally excited state (LE state), ICT vide guidance for the development of miniaturized lasers with state, and twisted ICT (TICT) state, which can be utilized to get higher performance. broad