第二章第二节 分子的立体结构1.3（The second chapter is about the second dimensional structure of molecules 1.3）.docVIP

第二章第二节 分子的立体结构1.3（The second chapter is about the second dimensional structure of molecules 1.3） This article is contributed by zhoulikt Ppt documents may experience poor browsing on the WAP side. It is recommended that you first select TXT, or download the source file to the local view. The second dimensional structure of molecules The Third Period Example 1: the orbital hybridization of the central atom in the following molecules: 1. () the same types are A.CO2 and SO2, B.CH4 and NH3, C.BeCl2 and BF3, D.C2H2 and C2H4 Example two: what is correct is that (example two: for SO2 and CO2, the correct thing is that A. is a linear structure, and.B. center atoms adopt SP hybrid orbitals. The central atoms adopt hybrid orbitals D ) C.S atoms and atoms do not have lone pair electrons. Atoms and C atoms do not have lone pairs of electrons, atoms and D.SO2 are V structures, and CO2 are linear junctions Example three: write Lewis molecular structure for the following is example three: write down the Lewis structure for the following molecules (for short said bonding electron, black dots represents no bonding for short-term bond electronic said black dots said the valence electron structure without bonding) and pointed out that the central atom may be used for the valence electron and pointed out that the hybrid orbital type central atom may be used, and to predict the geometry of molecules. The hybrid orbital type and predicts the molecular geometry. (1) PCl3 (2) BCl3 (3) CS2 (4) C12O PCl3:CI P CI.. CI (2) BCl3:.. B. CI. CI Cl.... (3) CS2:SP3 triangle cone.. SP SP3 straight line V shape.... SP2 Plane triangle .. S., =C, =S...... (4) C12O:Cl, O, CI:.... Complex theory introduction: complex theory introduction: experiment of 2-1 CuSO4 CuCl2.2H2O CuBr2 solid solution color blue green color white blue NaCl K2SO4 white colorless KBr white colorless dark brown white blue and colorless Thinking: the first three solutions are blue. Which substances are involved? On the basis of what?