清华大学有元素机化学第五章基元反应-3.pptVIP

5.5 成键配体的亲核反应 (Nucleophilic Attack on Ligands Coordinated to Transition Metals) 5.5.1.1 Nucleophilic attack at coordinated CO and related ligands 羰基配合物的亲核进攻反应 * H负离子进攻羰基的碳原子－生成甲酰基配合物 * OH-离子进攻羰基碳原子－生成羟羰基配合物 * Amines attack metal carbonyls to form carbamoyl complexes * Alkyl- and aryllithium attack metal-bound CO to generate acyl “ate” complexes Nucleophilic Attack on metal-bound isonitrile to form metal carbene complexes 5.5.1.2 卡宾的亲核进攻 5.5.1.3 配位烯烃的亲核进攻 Nucleophile olefin reaction in catalysis: The Wacker process 5.5.1.4 烯丙基配合物的亲核进攻 Allylic Alkylation:Nucleophilic Attack on