聚苯硫醚纤维在拉伸热定型中结构及性能.pdfVIP

Abstract The behaviorof determineda rheological polyphenylenesulfide(PPS)wasusing rheometerandtheinfluencesofshearrateand onthe capillary temperature ofPPSwerestudied．Itwasfoundthatthenon—Newtonian rheologicaiproperties indexWaslessthan1 andthe ofthe melt onthe reliabilityapparentviscosity Wasreducedwhilethe rateWaS viscousflow temperature shearing higher．The activationofPPSmeltWasdecreasedwiththeincreaseof ratewhen energy shearing the rate toonecertainvalueandthestructural indexWaS shearingreaching viscosity increaSe decreasedwiththe oftemperature． PPSresinused Inthis domestic Was to PPS filament paper,the preparespun by PPSfiber melt kindsof were the spinning,different samplespreparedbychanging of andheat influenceofdraw ratio processdrawing seRing．The temperature，draw andheat onthe ofPPSwas studied settingtemperatureproperties systematicallyby differential scanningcalorimetry(DSC)，velocitymeter，polarizedlightmicroscopy and tothecharacteristicsofdomesticPPS X-raydiffraction(XRD)，according resin, the of andheat Wasmade．Theresultsshowthatthe optimumprocessdrawing setting failurestressofPPSfibercarlreachto4．5cN／dtexinthis anddrawratio、draw