硫铝酸盐水泥与硅酸盐水泥复配性能研究.docx

．枷渗∞俐T水泥实用技术参考手册一253一誊蓬霭嚣瓢萤翻荫嗣_—————————l—●—__l—●—●●l__————___II●-l__硫铝酸盐水泥与硅酸盐水泥复配性能研究杨林u，严云1r，胡志华1,2，周科1，李正银1f1．西南科技大学材料科学与工程学院，lⅡt JiI绵阳621010； 2．西南科技大学四川省非金属复合与功能材料重点实验窒一省部共建国家重点实验室培育基地，四川绵阳621010)摘要：基于硫铝酸盐水泥、硅酸盐水泥各自的特点，研究了二者复配后的标准稠度用水量、凝结时间、水化热效应、胶砂 强度、膨胀性、水化产物的物相及微观形貌。结果表明，复配水泥的标准稠度用水量因复配比例不同而变化，凝结时间相 对于占主导地位的单组分水泥明显缩短；复配水泥的早期水化速率得到提高，ld、7d的水化放热量均低于占主导地位 的单组分水泥：28d抗压、抗折强度低于任何单组分水泥；膨胀性的大小取决于两种水泥的复配比例；硫铝酸盐水泥与 硅酸盐水泥的复配使二者的水化相互促进，随着硫铝酸盐水泥掺量的增加，Ca(OH)2相的衍射峰减弱，AFt相的衍射峰 增强：纯硅酸盐水泥水化后的微现形貌是致密的，而与硫铝酸盐水泥复配后则出现微观裂纹。关键词：水泥；复配；性能；水化Abstract：The properties of a composite cement with Portland cement and sulfoaluminate cement，including of the water requirement of normal consistency，setting time，hydration thermal effect，mortar strength，expansibility，phase and micro morphology of hydration products were studied．The results showed that the water requirement of normal consistency of compound cement was influenced by proportion of two kinds of cements．The setting time was shortened remarkably relative to unitary eement．The early hydration rate of compound cement was improved，the hydration heat of l d，7d was lower than unitary．cement．The 28d eompressive／flexural strength was less than pure Portland cement or sulphoaluminate cement．The proportion of cements varied the expansion ratio of compound cement．Hydration could be promoted as their composite， diffraction peak of Ca(OH)2 decreased with sulphoaluminate cement content increasing while AFt peak enhances．Thehydration products of unitary Portland cement was dense，however，micro—cracks could be observed，owing to the composite with sulphoaluminate cement．Key words：cement；composite；performance；hydrationFirst authors address：School of Materials Science and Engineering，Southwest University of Science and Technology，Mi—anyang 621010，Sichuan，China中图分类号：TQl72．11 文献标识码：A 文章编号：1002—9877(2012)07—0007-04O引言硫铝酸盐水泥为快硬42．5级水泥，记为SAC。两种水 硅酸盐水泥以硅酸钙矿物为主，由于其凝结时问泥皆购于四川地区，其化学成分见表1。较