温度对80SS油管钢腐蚀行为的影响.pdfVIP

· 34。 Jan．2008 Electroplating Pollution Control Vo1 ． 28 No．1 · 腐蚀与防护· 日 皿 度对 80SS油管钢 腐蚀 行 为 的影 响 Effect of Temperature on Corrosion Behavior of 80SS Oil Pipe Steel 田 伟 ， 谢发勤 ， 严密林 ， 周卫军。 (1．西北工业大学航空学院，陕西西安710072；2，中国石油天然气集团公司 管材研究所，陕西西安710065；3．西安石油大学材料学院，陕西西安710065) TIAN Wei ， XIE Fa-qin ， YAN Mi-Iin ， ZHoU Wei-jun (1．School of Aeronautics，Northwest Polytechnology University，Xi’an 7 1 0072，China； 2．The Key Lab for Mechanical and Enviroment Behavior Research CNPC，Xi’an 7 1 0065．China： ， 3．Department of Material Science and Engineering，Xi’an Petroleum University，Xi’an 710065， China) 摘要：模拟含H S／C02高温高压井下腐蚀环境，研究温度对80SS油管钢腐蚀行为的影响。结果表明：随着温度升高，80SS 油管钢的腐蚀速率呈现先增大后减小的趋势，在100 时腐蚀速率达到最大(6．13 mm／a)；150 时腐蚀速率下降到4．14 mm／a。随着温度升高，材料表面形成的腐蚀产物膜由致密、覆盖均匀逐渐变得颗粒粗大且疏松，-3温度超过100 时，腐蚀产 物膜又变得颗粒较小且致密；膜的厚度也呈现先增加后减小的趋势；80SS油管钢的腐蚀形态为均匀腐蚀；在温度低于100℃ 时腐蚀产物膜主要由FeCO，和FeS 组成；高温(150％)时，腐蚀中夹杂了Fe的氧化，产物膜主要由FeO(OH)、FeCO 和 FeS∽组成。 关键词：腐蚀；高温高压；H S／CO Abstract： The effects of temperature on corrosion behavior of 80SS oil pipe steel are investigated by simulating the real well high— temperature and pressure corrosion environment of muhiphase H2 S／CO2．The results show that the corrosion rate of 80SS oil pipe steel has a tendency from arising to falling with temperature rising．When the temperature is 100％，the corrosion rate is at maximum value (6．13mm／a)，and the corrosion rate will drop to 4．14 mm／a at 150％．The corrosion films wil be from compact and uniform to loose and have eoalffse grains with the rising of temperature，but when the temperature is above 100％，the corrosion films will become compact and uniform again．The thickness of corrosion films has a tend