新型线性嵌段共聚改性有机硅整理剂应用对比研究2011.docVIP

新型线性嵌段共聚改性有机硅整理剂应用对比研究 吴以榜1，王树根1，武晋2 （1 江南大学 生态纺织教育部重点实验室，江苏无锡，214122。2 欣悦印染有限公司，浙江嘉兴，314016） 摘要：为了提供新型线性嵌段共聚改性有机硅的生产实际应用参考，本文对比了一种新型线性嵌段共聚改性有机硅整理剂LBMS与市场上常见的几类改性有机硅整理剂相同条件下整理织物的应用性能。考察了棉织物、涤纶织物整理后的黄变、色变、落色性、手感撕破强力耐洗涤性TS190.2 文献标识码：A Comparative study of application of new linear block modified silicone copo-lymer finishing agent Wu Yi-bang1, Wang Shu-gen1, Wu Jin2 (1. Key Laboratory of Eco-Textile, Ministry of Education, Jiangnan University, Wuxi 214122, China; 2. Xinyue DyeingFinishing Co.,Ltd, Jiaxing 314016, Zhejiang, China) Abstract: In order to provide a reference of practical production application of a new linear block mo-dified silicone copolymer, this article compares the performance of fabric treated under the same condit-ions with new linear block modified silicone copolymer finishing agent (LBMS) and the market comm-on types of modified silicone finishing agents. Study the application performance of treated cotton and polyester fabric:yellowing, color change, resistance to losing color, hand, hydrophilic, tear strength, resis-tance to washing and recovery of crease resistant. The results showed that: the new linear block modifi-ed silicone copolymer finishing agent (LBMS) has a good overall application performance and it is a n-ew type of modified silicone finishing agent. This article provides a reference for the industrialization a-pplication of such finishes. Key words: linear block; modified silicone; applications; comparation 有机硅柔软剂在纺织品上大量使用，多数有机硅柔软剂整理后的织物呈疏水性，穿着时感到闷热，且难以洗涤。为此开发了亲水性的改性有机硅柔软剂，目前的亲水性改性方法多是采用聚醚类改性有机硅柔软剂，这对亲水性有显著改善，但其提供的柔软性和整理效果耐久性较差[1.2]。近年来，已发展到将多种活性基团共同使用，使其兼具多种活性基团的优点。例如聚醚一氨基改性有机硅柔软剂可同时赋予织物吸湿，抗静电和柔软效果，可以减少或不用乳化剂。环氧一聚醚改性有机硅柔软剂赋予织物柔软、滑爽、抗污和抗静电性能。氨基一环氧基改性有机硅柔软剂，使织物平滑、柔软，提高织物的耐洗性和抗静电性[3]。而最新出现的新型线性嵌段共聚改性有机硅整理剂可以解决柔软性、亲水性和耐久性这三个方面的矛盾，这是很有实际意义的助剂研发新进展。 为了考察这种新型线性嵌段共聚改性有机硅整理剂的工业化应用情况，我们在生产中进行了对比实验。考察了棉织物、涤纶织物整理后的黄变、色变、落色性、手感撕破强力耐洗涤性1 试验 1.1 材料及仪器 织物 20s×16s+70D/108×56全棉弹力纱卡漂白布、黑色布，240T涤纶春亚纺漂白布、黑色布。 药品 新型线性嵌段共聚有