高强高导铜锡合金的制造及性能研究.docVIP

高强高导铜锡合金的制造及性能研究 摘 要：随着现代工业的飞速发展，对高强度、高硬度、耐热、耐磨、导热的铜合金的需求越来越迫切。要求该类材料在满足其使用强度的前提下，尽量提高材料的电导率(80％IACS以上)。目前这类合金广泛应用于引线框架材料、高速电力机车架空导线、电接触头和焊接材料、发电机组、锅炉衬料等。 本文介绍了将合金元素直接加入有芯工频感应电炉的方法熔炼高强高导铜合金，既降低了成本又提高了生产效率，满足了工业化大生产的要求。采用立式半连续铸造和快速水冷的方法获得由Φ150mmX5000mm的连铸棒材；采用反向水封挤压工艺得到热挤压棒材；再经过冷拔得到高强高导铜合金成品材。 本文介绍了共还原沉淀法制得Cu- Sn 合金负极材料Cu6Sn5 和Cu6Sn4,并分别进行不同时间的时效处理, 对所得样品进行XRD 分析、场发射SEM 图像观察和恒流充放电性能测试。结果表明, 随着时效时间的延长, 样品相组成的均质性和电化学活性都得到了提高, 300 min 时效处理的Cu6Sn5 和Cu6Sn4 试样的第一周比容量分别为267.5mA·h/g 和342.0mA·h/g, 比20 min 时效处理试样相应值分别增加了12.7%和17.4%。另外, 增加惰性元素Cu的含量, 也会改善合金的电化学性能, 增加其循环稳定性。 关键词: Cu- Sn 合金;共还原沉淀法;时效处理;负极材料;锂离子电池  With high strength and high conductivity copper tin alloy manufacturing and performance study Abstract：ith the rapid development of modern industry, the high strength, high hardness, heat resistance, wear resistance, thermal conductivity of the copper alloy demand has become more and more urgent. This kind of alloy are widely used in the lead frame material, high speed electric locomotive overhead conductors, electric contact head and welding material, generators, boiler lining, etc. Now require this materials on the premise of meet the intensity of use, try to increase the conductivity of the material (more than 80% IACS). By adding alloying elements directly to have a way of core power frequency induction furnace melting with high strength and high conductivity copper alloys, and reduced the cost and improve the production efficiency, meet the requirements of the industrialized production. Adopt the method of vertical semi-continuous casting and rapid water obtained fromΦ150 mm*5000mm casting bar; Reverse water seal extrusion process for hot extrusion rod; After cold drawn material with high strength and high conductivity copper alloy material. Precipitation method, this paper adopts the total reduction of Cu - Sn alloy anode materials Cu6Sn5 and Cu6Sn4, and carries on the different time of aging treatment, respectively, of the samples o