内外增韧环氧树脂酸酐体系固化行为和性能-北京粘接学会.pdf

Curing Behaviors and Properties of an Extrinsic Toughened and an Intrinsic Toughened Epoxy/anhydride System 内/外增韧环氧树脂/酸酐体系固化行为和性能 CHENG Jue, FAN Meng-jin, YANG Tao, LIU Jia-lin, LI Xiang-yuan, * ZHANG Jun-ying (Key Laboratory of Carbon Fiber and Functional Polymers, Ministry of Education, Beijing University of Chemical Technology, Beijing 100029, P.R. China) 程珏，樊孟金，杨涛，刘嘉林，李相元，张军营* （教育部碳纤维及功能高分子重点实验室，北京化工大学，北京 100029 ，中国） Abstract A series of extrinsic toughened epoxy resins based on diglycidyl ether of bisphenol-A and 1,4-butanediol epoxy resin (DGEBA and DGEBD) and a series of intrinsic toughened epoxy resins based on diglycidyl ether of ethoxylated bisphenol-A containing two and six oxyethylene units (DGEBAEO-2 and DGEBAEO-6) were prepared by using hexahydrophthalic anhydride (HHPA) as curing agent and tris-(dimethylaminomethyl) phenol (DMP-30) as accelerator. The curing behaviors, dynamic mechanical properties and mechanical properties of the two series of epoxy resins were comparatively studied by non-isothermal DSC, DMTA and tensile test; the shape-memory properties of the intrinsic toughened epoxy resins were investigated by fold-deploy shape memory test. The results showed that the activation energy of DGEBA/DGEBD/HHPA/ DMP-30 at high fractional conversion changed much higher than that of DGEBAEO-2/ HHPA/DMP-30, according to non-isothermal DSC. The glass transition temperature of the extrinsic toughened epoxy resins was higher than that of the intrinsic toughened epoxy resins, according to DMTA. The tensile strength of the intrinsic toughened epoxy resins was lower than that of the extrinsic toughene