新型非离子型自乳化水性环氧树脂固化剂的合成与表征-中国电镀网.pdfVIP

40 3 Vol. 40 N o. 3 2010 3 PA INT COAT INGS INDUSTRY M ar. 2010 1, 3, 4 1, 2, 3 1, 2, 3 1, 3, 4 2, 3 邹海良 , 张亚峰 , 邝健政 , 刘 军 , 徐宇亮 ( 1. 中科院广州化学研究所, 广州 510650; 2. 中科院广州化灌工程有限公司, 广州 510070; 3. 广 省化学灌浆工程技术研究开发中心, 广州 510650; 4. 中国科学院研究生院, 北京 100039) : , , , , : , , , , , : ; ; ; ; : TQ 6304 : A : 0253- 4312( 2010) 03- 0021- 05 Synthesis and Characterization of New Nonionic Type Self- emulsifiedW aterborne Epoxy Curing Agent 1, 3, 4 1, 2, 3 1, 2, 3 1, 3, 4 2, 3 Zou Hailiang , Zhang Y af ng , Kuang Jianzh ng , Liu Jun , Xu Yuliang ( 1. Guangzhou Institute of Chem istry CAS, Guangzhou 510650, Ch ina; 2. Guangzhou Chem ical Grouting Eng ineering Co. LTD., CAS, Guangzhou 510650, China; 3. Guangdong rov. E. R. C.f or Chem ical Crouting, Guangzhou 510070, China; 4. Graduate School of ChineseAcademy of Sciences, Beijing 100039, China) Abstract: A n w non ionic typ s lf- mulsifi d w at rborn poxy curing ag nt has b n d v lop d by r action of octad canam in and th thyl n glycol diglycidyl th r to syn th siz an poxy compound, w h ich has a long hydrophobic alkyl chain on th N atom and t rm inat d poxy groups. th n block dw ith th r sults show that th synth siz d poxy curing ag n t provid s good hydroph ilicity w ithout xt rnal n utraliz r, and xc ll nt mulsify ing p rformanc to poxy r sin. B caus of its hydrophob ic long alkyl chain and hydroph il ic am in , hydroxyl and th r groups, th curing ag nt can act lik a surfactant. Th two compon nt syst m s of synth siz d poxy curing ag nt and liqu id poxy r sin