离子色谱-串联质谱用于净水树脂中14种胺类固化剂-现代仪器与医疗.pdfVIP

检验检测 2014年  第20卷   第1期 离子色谱-串联质谱用于净水树脂中14种 胺类固化剂迁移量方法的建立及应用 刘旭辉　唐树田　高峰　刘鑫　程喜明　张朝晖　刘岩 （北京出入境检验检疫局检验检疫技术中心，北京　100026 ） [ 摘　要 ]　欧盟最新指令新法规(EU) No.10/2011 对胺类物质的迁移限量进行了规定。本文研 究饮用水净化树脂中14 种胺类固化剂的迁移量检测方法，选用高容量阳离子交换柱IonPac CS17 (2mm) 进行分离，以甲烷磺酸(MSA) 为淋洗液，采用梯度淋洗。淋洗液经过抑制器后直 接进入质谱(ESI-MS) ，正离子模式进行检测。建立了一种同时测定树脂中14 种胺类固化剂迁 移量的离子色谱- 串联质谱方法。该方法的加标回收率为76.5%~104.8% ，相对标准偏差（RSD ） 为0.94%~10.7% ，该方法简便快速，可用于树脂中胺类固化剂迁移量的同时测定。 [ 关键词 ]　胺类固化剂；饮用水净化树脂；离子色谱/ 串联质谱法 中图分类号：O657　文献标识码：A　文章编号：2055-5200(2014)01-064-05 Doi：10.11876/mimt201401017 Detection of the migration of 14 amines curing agent in water purification resins by ion-chromatography/electrospray tandem mass spectrometry　LIU Xu-hui, TANG Shu-tian, GAO Feng, LIU Xin, CHENG Xi-ming, ZHANG Zhao-hui, LIU Yan. Technical （ Center, Beijing Entry-Exit Inspection and Quarantine Bureau, Beijing, 100026 ） [Abstract]　In the new EU Directive (No.10/2011), amines curing agent in water purification resins was given their limitations. In this paper, a method was established to simultaneously determine the migration of 14 amide curing agent used in the resin for water purification by using ion- chromatography/electrospray tandem mass spectrometry(IC/ESI/MS). Amide curing agents were separated with high capacity and cation exchange column using MAS eluent gradient online from EGC. The recoveries are in the range of 76.5%~104.8% while the relative standard deviation (RSD) ranges from 0.94% to10.7%. This method is simple and rapid, which is applicable for the simultaneous determination of amide curing agent migration of 14 amides curing agent used in the resin for water purification. [Key words] amines curing agent water purification resins ion-chromatography/electrospray 　 ； ； tandem mass spectrometry 由于普遍认识到反复烧开的水会引起致癌物质