两种褐藻对废水中铅、铜的吸附机理研究 study on the mechanism of pb( ⅱ ) and cu( ⅱ ) biosorption by two brown algae.pdfVIP

两种褐藻对废水中铅、铜的吸附机理研究 周洪英h2， 李娜1， 王学松1， 单爱琴2 (1．淮海丁学院化学J：稃学院．江苏连云困矿业大学环境与测绘学院．江苏徐州221008) 摘要：运用批吸附技术研究了海带Laminaria japonica和裙带菜Undariapinnatifida对水溶 液中Pb2+、Cu2+的吸附特性。结果表明：硝酸钙预处理后，两种海藻对Cu2+的吸附容量降低 28％左右，对Pb2+的吸附容量下降lO％左右。用化学改性方法确定不同官能团对生物吸附的 贡献，结果表明羧基对两种海藻吸附Pb2十的贡献大于胺基和羟基。共存阴离子影响海藻对 Cu2+的吸附，CuCl2的吸附速率和吸附容量大于Cu(N03)2和CuS04。 关键词：褐藻；生物吸附；重金属；平衡；动力学 中图分类号：X703文献标识码：A文章编号：1673—1689(2012)01--047—08 ontheMechanismof Study Pb(11)and TwoBrown by Algae Lf 2 ZHoU Nal，W_ANG Hong—yingⅥ， Xue—son91，SHAN Ai—qin (1．SchoolofChemical Instituteof 222005，China：2．SchoolofEnvironmentSci— Engineering，HuaihaiTechnology，Lianyungang enceand of and Informatics，ChinaUniversityMiningTechnology，Xuzhou221008，China) Spatial Abstract：Thetoremoveleadand from solutionbrownLamina— ability copperaqueous by algae Undaria were in were ria and this drawnasfol- japonica pinnatifidainvestigatedstudy．Results with oftwo for lows：PretreatmentCa(N03)2，the Cu(II)decreased absorptioncapacity algae Pb(U)decreased10％．Thecontributionoffunctionalinthe by28％，for by groups biosorp- tion wasconfirmedchemicalmodificationofthe functionalof process by groups．The group was forthe oftwo heretowardsPb2