镀镍板镀层的辉光放电光谱法解析.pdfVIP

镀镍板镀层的辉光放电光谱法解析 ·1 · 镀镍板镀层的辉光放电光谱法解析 刘 洁 侯环宇 安 晖 蔡 啸 杨慧贤 （河北钢铁技术研究总院，河北石家庄 050000 ） 摘 要 本方法采用辉光放电光谱法对镀镍板样品进行逐层剥离，根据样品随着深度的辉光放电积分谱图，可以对 镀镍板结构总体进行判定，还可以对镀镍板表面进行放大分析，了解镀镍板的基本结构。利用射频辉光放电光谱仪 逐层分析的特点，对两种镀镍板进行了研究探讨，分析了镀镍板的镀层厚度及质量，利用辉光光谱仪分析镀镍板镀 层质量相对稳定，精密度试验中其RSD 值均小于3%，通过XRF 荧光光谱仪对其结果进行比对，比对结果基本一 致。同时还分析了镀镍板基板成分，通过ICP 光谱仪对其结果进行比对，比对结果基本一致。 关键词 辉光放电光谱法，镀镍板，镀层厚度，镀层质量，基板成分 Analysis of the Nickel Plate by Glow Discharge Optical Atomic Emission Spectrometry Liu Jie, Hou Huanyu, An Hui, Cai Xiao, Yang Huixian (Hebei General Research Institute of Iron and Steel Technology, Shijiazhuang 050000, China) Abstract When nickel plate sample was ablated layer by layer by glow discharge optical atomic emission spectrometry, formula integral was set according to glow discharge integral spectrum from sample surface to its center for the purpose of judging the overall of the nickel plate,and analysising the amplification surface, and also understanding the basic structure of nickel-plated sheet.Two cases in the analysis of surface were studied and discussed by meand of radio frequency glow discharge optical emission spectrometry,which can analyze the sample surface layer by layer.The thickness and mass of coating in nickel plate were analyzed, the nickel plate coating mass is relatively stable, the precision test the RSD values were less than 3%, To compare its results by XRF fluorescence spectrometer, the results are basically the same. It also analyzes base-plate composition of the nickel plate, to compare its results by ICP spectroscopy, comparison results are basically the same. Key words glow discharge spectro