聚苯乙烯的工艺合成.doc

聚苯乙烯的工艺合成 摘 要 可发性聚苯乙烯（Expandable PolyStyreneEPS）通称聚苯乙烯和苯乙烯系共聚物，是一种树脂与物理性发泡剂和其它添加剂的混合物。可发性PS可被加工成低密度（0．7—10．0ib／ft3）的泡沫塑料剂品。最常见的发性聚苯乙烯是含有作为发泡剂的戊烷的透明PS粒料。 关键词：可发性聚苯乙烯；悬浮聚合；物料衡算；工艺设计 ABSTRACT Expandable Polystyrene (Expandable PolyStyrene, referred to as EPS) commonly known as the Department of polystyrene and styrene copolymer is a resin with the physical blowing agent and other additives mixture. EPS can be processed into low-density (0.7-10.0ib/ft3) goods of the foam agent. The most common is to be made of polystyrene with n-pentane as a blowing agent aggregates of transparent PS. The design for the annual production capacity of 10，000 tons can be made of polystyrene polymerization process design section, the reaction mechanism is free radical polymerization, suspension polymerization process used to styrene as monomer, water suspension medium done using one-step production of low-temperature suspension polymerization process. This method is a styrene monomer, initiator, dispersing agent, water, blowing agent and other auxiliaries to join reactor, the polymer containing a foaming agent, after the resin particles by washing, centrifugal separation and drying, the system may be made of polystyrene beads products; in this section based on the polymer material balance, heat balance, equipment selection, the mapping of control points with the flow chart, diagram and layout of piping plans and the preparation of the design specification and calculation of the book. Key Words：Expandable PolyStyrene；Suspension Technique;Craft calculation；Technological design 目 录 摘 要 I 第1章 前言 III 1.1概述 III 1.2国际EPS供需现状 III 1.3国内EPS现状 III 1.4前景展望 III 第2章 EPS概述 III 2.1发泡聚苯乙烯 III 2.2发泡聚苯乙烯基本性能 III 2.2.1力学性能 III 2.2.2绝热性能 III 2.2.3化学性能 III 2.2.4应用范围 III 第3章 合成工艺 III 3.1工艺原理 III 3.1.1实施方案 III 3.1.2工艺路线 III 3.1.3工艺流程 III 3.1.4反应原理 III 3.2发泡聚苯乙烯技术工艺比较 III 3.2.1塔式本体聚合技术 III 3.2.2添加少量溶剂的单釜连续本体聚合技术 III 3.2.3苯乙烯的悬浮聚合 III 3.2.4苯乙烯种子法悬浮聚合 III 3.3发泡聚苯乙烯生产工艺 III 3.3.1一步法聚合工艺 III 3.3.2二步法聚合工艺 III 3.