丙烯酸钙与矿物掺合料复合对水泥强度及抗蚀性能的影响.docVIP

摘 要 在水泥中添加矿物掺和料不仅可以节省熟料而且通过一定的技术手段可以提高水泥的性能，因此矿物掺和料受到人们的青睐。而聚合物改性水泥以其独特的粘结强度，抗腐蚀能力，及抗渗防水效果也在水泥领域占有重要地位。本论文结合矿物掺和料与聚合物的优点，研究了丙烯酸钙与矿物掺合料复合对水泥强度及抗蚀性能的影响。 实验采用以粉煤灰和矿渣为变量，丙烯酸钙为定量的方式根据水泥抗压强度与抗硫酸盐腐蚀性两个性能指标来探讨最优的矿物掺和料与丙烯酸钙的配比。又通过X射线衍射（XRD）与扫描电镜（SEM）两种材料测试方法来分析最优配比及异常配比对水泥水化性能的影响。经试验得出最优配比为： 关键词：矿物掺和料；聚合物；丙烯酸钙；抗压强度；抗硫酸盐侵蚀性  ABSTRACT Cement is an indispensable material in building industry. However, there are some defects in its hardened structure , for example, bigger fragility and more pores. These deficiencies result in poor durability of cement. In this experiment, we mainly study the monomer of acrylic calcium / magnesium. The monomer supplemented with auxiliaries (cross-linking agent, etc) possess low viscosity, good compatibility and cohesiveness with cement, etc. Adding this serous fluid to the cement can improve the physical and chemical performance and corrosion resistance of cement. Because there are polymers forming in the process of the body, and these polymers can fill pores in cement, Orthogonal test in this thesis is beneficial for us to select optimal acrylic calcium / magnesium and additives formula. Then in the basis of orthogonal test, we have researched the effect of cement on mechanical properties caused by the change monomer content . Finally, we use scanning electron microscopy (SEM)、 X-ray diffraction (XRD) and other testing methods to study the effect of optimal case on the cement hydration.It`s proved that the optimal ratio of acrylic calcium / magnesium is 5:5, while the initiator (potassium per-sulfate) is 3% (relative to the monomer), and for accelerant (trimethylamine) is 0, cross-linking agent (butyl acrylate)is 10%; Furthermore, the best monomer content is 1.0%. Keywords: ordinary portland cement; acrylate; organic monomer; compressive strength; corrosion resistance  目 录 摘要 I ABSTRACT II 1 前言 1 1.1 课题背景 1 1.2 水泥的抗硫酸盐侵蚀性…………………………………………………… ..2 1.2.1 水泥化学腐蚀的种类 2 1.2.2 水泥硫酸盐腐蚀的机理 3 1.2.3 提高水泥抗腐蚀性的方法 3 1.3 矿物掺合料水泥 4 1.3.1 矿物掺合料水泥的发展现状 1.