【精选】One-Pot Synthesis of Uniform Cu2O and CuS Hollow Spheres and Their Optical Limiting Properties.pdfVIP

Chem. Mater. 2008, 20, 6263–6269 6263 One-Pot Synthesis of Uniform Cu O and CuS Hollow Spheres and 2 Their Optical Limiting Properties Jining Gao,† Quanshui Li,‡ Huabo Zhao,† Lianshan Li,† Chunling Liu,‡ Qihuang Gong,‡ and Limin Qi*,† Beijing National Laboratory for Molecular Sciences, State Key Laboratory for Structural Chemistry of Unstable and Stable Species, College of Chemistry, and State Key Laboratory for Mesoscopic Physics, School of Physics, Peking UniVersity, Beijing 100871, People’s Republic of China Recei Ved May 23, 2008. ReVised Manuscript ReceiVed July 28, 2008 Uniform hollow spheres of Cu O and CuS were successfully synthesized by chemical transformation 2 of in situ formed sacrificial templates containing Cu(I) in aqueous solutions. The shell thickness of these hollow spheres can be adjusted through the choice of the bromide source used for the formation of intermediate templates. Specifically, thick-shell hollow spheres (about 130-180 nm in shell thickness) were obtained by using CuBr solid spheres as the templates, which were formed by the reduction of CuBr2 with ascorbic acid; on the other hand, thin-shell hollow spheres (about 20-25 nm in shell thickness) were obtained by using spherical aggregates consisting of the Cu+, Br-, and (C H ) N+ ions as the