CO-H 2 还原浮氏体的竞争行为研究.pdfVIP

CO-H 还原浮氏体的竞争行为研究 ·1 · 2 CO-H 还原浮氏体的竞争行为研究 2 王冬东 胡招文 严 明 黄雅萍 徐 健 吕学伟 白晨光 （重庆大学材料科学与工程学院，重庆 400044 ） 摘 要 本研究以浮氏体还原为对象，采用热重法实验研究在 850℃下，三种不同还原气氛下的还原机理，由此初 步探索 CO-H2 间的竞争行为。通过计算分析不同气体组成下，浮氏体还原转化率在0.1~0.5 范围内的经验机理函数 幂指数 n 和类化学速率常数的均值 k*，结合两种气体混合还原反应的速率与两种气体分别进行还原的速率的关系， 获得以下结论：本实验条件下浮氏体的还原遵守三维随机成核随后成长机理；在转化率 0.1~0.5 之间，随着转化率 的升高，三种还原气体组成下浮氏体的还原速率均呈增加的趋势，并且在各个还原度水平下，CO 气体的还原速率 最慢，CO-H 混合气体的还原速率最快但要小于 CO 与 H 单一成分还原速率的线性加和，H 气体的还原速率则介 2 2 2 于两者之间。 关键词 CO ，H2 ，浮氏体还原，热重分析 Competitive Behavior of Wustite Reduction by CO-H Mixture Gas 2 Wang Dongdong, Hu Zhaowen, Yan Ming, Huang Yaping, Xu Jian, Lv Xuewei, Bai Chenguang (College of Materials Science and Engineering, Chongqing University, Chongqing 400044, China) Abstract To explore competitive behavior of wustite reduction by CO-H2 initially, the reduction reaction of the wustitebased on TGAunder the temperature at 850 ℃ and three different gas compositions.Based on exponent n of mechanism function and the average value of based chemical rate constant k*, the relationship between the rate of using two gas mixed reductions and the rate of reduction of the two gases used respectively are analyzed. The results show that: Under the experimental conditions, the reaction is subject to random nucleation followed by growth of three-dimensional.When the conversion rate i