电镀镍磷合金及其电催化活性研究.PDFVIP

電鍍鎳磷合金及其電催化活性研究 防蝕工程　第二十一卷第四期　第273 ～ 280 頁　2007 年 12 月 Journal of Chinese Corrosion Engineering, Vol. 21, No. 4, pp. 273 ~ 280 (2007) 王世宗、林招松* Electrodeposition and Electrocatalytic Properties of Nickel-Phosphorus Alloys S. T. Wang, C. S. Lin* 本研究於檸檬酸浴中製備鎳磷合金，並探討其在酸性電解液中的電催化活性。結果顯 示檸檬酸浴中製備之非晶鎳磷合金在酸性電解液中同時具有優異電催化活性與耐蝕性。此 外，鍍層磷含量雖不受電流密度影響，但電催化活性隨電流密度提高而增加，且鍍層電催 化活性與吸附氫能力具有正相關性。隨著溶液溫度增加會降低鍍層電催化活性能力，顯示 升高溶液溫度不利於電催化反應發生，推測電極材料表面在高溫溶液中易生成氧化膜。 關鍵字：檸檬酸浴；鎳磷合金；電催化活性；吸附氫能力。 ABSTRACT Ni-P alloy coatings were electroplated from nickel citric baths, and their hydrogen evolution reaction in acid electrolytes was studied. Experimental results show that all Ni-P deposits studied were amorphous, and exhibited excellent electrocatalytic activity and corrosion resistance in acid electrolytes. The deposit phosphorus content hardly changed with the electroplating current density, whereas the electrocatalytic activity of the deposit increased with increasing electroplating current density. Moreover, the deposit that absorbed more hydrogen during cathodic polarization exhibited better electrocatalytic activity. Finally, the electrocatalytic activity of the deposit became poor when measured in the electrolytes at higher temperatures. This is likely to be due to the formation of a surface oxide film in the high-temperature electrolyte. Keywords: Nickel citric bath; Ni-P alloy coating; Electrocatalytic activity; Hydrogen adsorption capability. ˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍ