纳米气泡的形成及其对微细粒矿物浮选的影响-中南大学学报.PDF

第 48 卷第 1 期 中南大学学报( 自然科学版) Vol.48 No.1 2017 年 1 月 Journal of Central South University (Science and Technology) Jan. 2017 DOI: 10.11817/j.issn.1672-7207.2017.01.002 纳米气泡的形成及其对微细粒矿物浮选的影响 冯其明，周伟光，石晴 ( 中南大学 资源加工与生物工程学院，湖南 长沙，410083) 摘要：通过 1 个自制的、运用水力空化原理产生纳米气泡的发生装置，研究发现纳米气泡能够强化微细粒白钨矿 浮选。为了更好地认识纳米气泡的性质，运用 Malvern Nano ZS 90 纳米粒径电位分析仪研究放置时间、油酸钠浓 度、溶液 pH 以及空化时间对纳米气泡尺寸分布和Zeta 电位的影响。研究结果表明：纳米气泡能够在油酸钠溶液 稳定存在 1 h 以上，具有很强的稳定性；纳米气泡尺寸随着油酸钠浓度增高而减小，随着pH 增大而增大；表面 电负性则随着 pH 的增大不断增强；超过一定时间范围后，延长空化时间对纳米气泡的尺寸并无显著影响，这可 能是溶液中溶解气体在水相和气相中达到动态平衡所致。纳米气泡能够提高微细粒白钨矿的浮选速率和回收率。 关键词：纳米气泡；水力空化；白钨矿；浮选 中图分类号：TD952 文献标志码：A 文章编号：1672−7207(2017)01−0009−07 Formation of nano-bubbles and their influences on ultrafine mineral flotation FENG Qiming, ZHOU Weiguang, SHI Qing (School of Minerals Processing and Bioengineering, Central South University, Changsha 410083, China) Abstract: The enhancing effect of nano-bubbles in ultrafine scheelite flotation was studied using a homemade nano-bubble generator based on the hydrodynamic cavitation. The effects of storage time, NaOl concentration, pH value and cavitation time on nano-bubble size distribution and Zeta potential were studied through a Zetasizer nano ZS(Malvern Nano ZS 90). The results show that nano-bubbles can be stable in NaOl solution for more than 1 h. The average size of nano-bubble decreases with the increase of NaOl solution concentration, and increases as the pH values of solution raise. The electronegativity of nano-bubble is enhanced when pH values of solution