防水防油抗静电锦纶织物整理工艺的研究 the development of nylon fabrics with water and oil proof, anti-static properties.pdfVIP

Vol.35 No.2 14 染 整 技 术 Feb.2013 羧甲基棉织物对镍离子的吸附性能研究 1 1,2 1 1 1 闫永海 朱 平 赵明晓 张 林 董朝红 （1. 青岛大学“纤维新材料及现代纺织”国家重点实验室培育基地， 山东青岛 266071； 2. 武汉纺织大学化学与化工学院， 湖北武汉 430073） 摘 要：用烧碱和一氯乙酸对棉织物进行羧甲基化改性，制备一种离子交换纤维吸附水中镍离子，并研究 pH、吸附温度、吸附时间以及取代度等的变化对吸附性能的影响，同时对吸附动力学进行分析，探讨该离子交 换纤维的再生方法。实验证明：羧甲基棉织物对镍离子具有良好的吸附性能，吸附量可通过调节吸附条件得到 控制，并具有良好的再生性能，可循环使用，是一种环保、高效的离子交换材料。 关键词： 离子交换纤维；羧甲基；镍离子；吸附量 中图分类号：TS 190.11 文献标识码：A 文章编号： 1005-9350(2013)02-0014-05 The study of adsorption properties for carboxymethyl cotton fabric to nickel ions 1 1,2 1 1 1 YAN Yong-hai , ZHU Ping , ZHAO Ming-xiao , ZHANG Lin , DONG Zhao-hong (1. Advanced Fibers ＆ Modern Textile Cultivation Base for State Key Lab, Qingdao University, Qingdao 266071, China; 2. School of Chemistry and Chemical Engineering, Wuhan Textile University, Wuhan 430073, China) Abstract：An ion-exchange fiber which can absorb nickel ions in water was prepared by modifying cotton fabric with NaOH and chloroacetic acid. Technical parameters such as pH, reaction time, reaction temperature and the degree of substitution (DS) was studied to investigate the effect on adsorption capacity. The paper also studied the adsorption kinetics and the regeneration method. The results showed that carboxymethyl cotton fabric has good adsorption performance and adsorption capacity for the nickel ion and the adsorption capacity can be controlled by altering the experimental conditions. The material can be recycled. It is an environmental friendly, efficient ion-exchange material. Key words：ion-e